Enantioselective and enantiospecific transition-metal-catalyzed cross-coupling reactions of organometallic reagents to construct C–C bonds
The stereocontrolled construction of C− C bonds remains one of the foremost challenges in
organic synthesis. At the heart of any chemical synthesis of a natural product or designed …
organic synthesis. At the heart of any chemical synthesis of a natural product or designed …
N-Heterocyclic carbene (NHC) ligands and palladium in homogeneous cross-coupling catalysis: a perfect union
N-Heterocyclic carbene (NHC) ligands and palladium in homogeneous cross-coupling
catalysis: a perfect union - Chemical Society Reviews (RSC Publishing) DOI:10.1039/C1CS15088J …
catalysis: a perfect union - Chemical Society Reviews (RSC Publishing) DOI:10.1039/C1CS15088J …
The Suzuki-Miyaura reaction after the Nobel prize
IP Beletskaya, F Alonso, V Tyurin - Coordination Chemistry Reviews, 2019 - Elsevier
Synthetic organic chemistry experienced a significant advance in the last quarter of the 20th
century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility …
century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility …
Why is ferrocene so exceptional?
D Astruc - European Journal of Inorganic Chemistry, 2017 - Wiley Online Library
The appearance of ferrocene in the middle of the 20th century has revolutionized
organometallic chemistry and is now providing applications in areas as varied and …
organometallic chemistry and is now providing applications in areas as varied and …
Forever young: the first seventy years of ferrocene
P Štěpnička - Dalton Transactions, 2022 - pubs.rsc.org
The discovery of ferrocene,[Fe (η5-C5H5) 2], seventy years ago has significantly influenced
chemical research and provided a key impetus for establishing and rapidly expanding …
chemical research and provided a key impetus for establishing and rapidly expanding …
Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals
P Loxq, E Manoury, R Poli, E Deydier… - Coordination Chemistry …, 2016 - Elsevier
Axially chiral biaryl structures are unique systems encountered in various synthetic
compounds such as BINAP and BINOL, polymers, but also in natural products presenting a …
compounds such as BINAP and BINOL, polymers, but also in natural products presenting a …
Palladium catalyzed asymmetric Suzuki–Miyaura coupling reactions to axially chiral biaryl compounds: Chiral ligands and recent advances
D Zhang, Q Wang - Coordination Chemistry Reviews, 2015 - Elsevier
Axially chiral biaryls exist widely in bioactive natural products and auxiliary ligands for
homogeneous catalysis. The particular spatial arrangement of the two aromatic rings in the …
homogeneous catalysis. The particular spatial arrangement of the two aromatic rings in the …
Cyclic iron tetra N-heterocyclic carbenes: synthesis, properties, reactivity, and catalysis
TP Schlachta, FE Kühn - Chemical Society Reviews, 2023 - pubs.rsc.org
Cyclic iron tetracarbenes are an emerging class of macrocyclic iron N-heterocyclic carbene
(NHC) complexes. They can be considered as an organometallic compound class inspired …
(NHC) complexes. They can be considered as an organometallic compound class inspired …
Selective syntheses of planar-chiral ferrocenes
D Schaarschmidt, H Lang - Organometallics, 2013 - ACS Publications
Planar-chiral ferrocenes are widely applied in catalytic asymmetric transformations in
scientific research as well as in industry. A plethora of different methodologies have been …
scientific research as well as in industry. A plethora of different methodologies have been …
Hindered biaryls by C–H coupling: bisoxazoline-Pd catalysis leading to enantioselective C–H coupling
A new Pd-catalyzed C–H/C–B coupling of sterically hindered heteroarenes and arylboronic
acids has been identified. The newly established Pd (OAc) 2/bisoxazoline/TEMPO system …
acids has been identified. The newly established Pd (OAc) 2/bisoxazoline/TEMPO system …