Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements

J Zhou - Coordination Chemistry Reviews, 2016 - Elsevier
Heterometallic chalcogenides are no longer limited to only transition metals or main group
metal chalcogenides. Recent research has showed that combinations of lanthanides and …

Large Mid-Infrared Second-Harmonic Generation in Eu (II)-Based Quaternary Chalcogenides

S Jana, EA Gabilondo… - Chemistry of …, 2024 - ACS Publications
Complex metal chalcogenides have received growing attention for second-harmonic
generation (SHG) activity arising from their noncentrosymmetric structures. In this area, the …

Noncentrosymmetric chalcogenides BaZnSiSe4 and BaZnGeSe4 featuring one-dimensional structures

W Yin, AK Iyer, C Li, J Yao, A Mar - Journal of Alloys and Compounds, 2017 - Elsevier
The two quaternary tetrel-containing selenides BaZnTtSe 4 (Tt= Si, Ge) have been prepared
by reactions of BaSe, ZnSe, Tt, and Se at 1023 K. They adopt noncentrosymmetric structures …

Bi13S18I2: (Re)discovery of a Subvalent Bismuth Compound Featuring [Bi2]4+ Dimers Grown in Sulfur/Iodine Flux Mixtures

R Groom, A Jacobs, M Cepeda, R Drummey… - Chemistry of …, 2017 - ACS Publications
Reactions of bismuth in sulfur/iodine flux mixtures were explored at various temperatures
and iodine concentrations. The observed products include Bi2S3, BiSI, and Bi13S18I2. The …

CsCdInQ3 (Q = Se, Te): New Photoconductive Compounds As Potential Materials for Hard Radiation Detection

H Li, CD Malliakas, JA Peters, Z Liu, J Im… - Chemistry of …, 2013 - ACS Publications
Two new compounds CsCdInQ3 (Q= Se, Te) have been synthesized using a
polychalcogenide flux. CsCdInQ3 (Q= Se, Te) crystals are promising candidates for X-ray …

Mild solvothermal syntheses and characterization of layered copper thioantimonates (III) and thioarsenate (III)

C Zhang, M Ji, SH Ji, YL An - Inorganic Chemistry, 2014 - ACS Publications
The new copper thioantimonates (III) and thioarsenate (III) Rb2Cu2Sb2S5 (1),
Cs2Cu2Sb2S5 (2), and Rb8Cu6As8S19 (3) have been synthesized solvothermally …

Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen …

G Panigrahi, G Morrison, MD Smith… - Inorganic …, 2024 - ACS Publications
We report a detailed structural study of a series of five new quaternary Eu (II)-containing
mixed chalcogenide phases, Eu2SiSe0. 85S3. 15, Eu2SiSe2. 4S1. 6, Eu2SiSe2. 6S1. 4 …

New Quaternary Rare-Earth Chalcogenides BaLnSn2Q6 (Ln = Ce, Pr, Nd, Q = S; Ln = Ce, Q = Se): Synthesis, Structure, and Magnetic Properties

K Feng, X Zhang, W Yin, Y Shi, J Yao, Y Wu - Inorganic Chemistry, 2014 - ACS Publications
The first series of rare-earth chalcogenides with mixed-valence Sn atoms, namely the Ba Ln
Sn2Q6 (Ln= Ce, Pr, Nd, Q= S; Ln= Ce, Q= Se) compounds, were synthesized via …

Crystal and electronic structures, and photoluminescence and photocatalytic properties of α-EuZrS 3

SP Guo, Y Chi, JP Zou, HG Xue - New Journal of Chemistry, 2016 - pubs.rsc.org
A new phase of EuZrS3 (α phase) was obtained via a high-temperature solid-state reaction.
It crystallizes in the orthorhombic space group Pnma with a= 8.465 (3), b= 3.808 (1), c …

A series of new lanthanoid thioarsenates: insights into the influence of lanthanide contraction on the formation of new lanthanoid thioarsenates

J Zhou, RQ Zhao, T Yang, X Liu, HP **ao, HH Zou… - Dalton …, 2015 - pubs.rsc.org
A series of new lanthanoid thioarsenates [Ln (teta)(μ–η1: η2: η1-AsIIIS3)] n {Ln= Ce (Ia), Pr
(Ib), Nd (Ic), and Sm (Id); teta= triethylenetetramine} and [Ln (teta)(en)(μ–η1: η1: η1-AsVS4)] …