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Optical phenomena in molecule-based magnetic materials
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …
deals with magnetic materials based on molecular species, ie, organic radicals and metal …
Predicting valence tautomerism in diverse cobalt–dioxolene complexes: elucidation of the role of ligands and solvent
The ability of molecular switches to reversibly interconvert between different forms promises
potential applications at the scale of single molecules up to bulk materials. One type of …
potential applications at the scale of single molecules up to bulk materials. One type of …
Switching metal complexes via intramolecular electron transfer: connections with solvatochromism
VL Nadurata, C Boskovic - Inorganic Chemistry Frontiers, 2021 - pubs.rsc.org
Metal complexes that can exist in two different charge distributions often exhibit dramatic
color changes when switched between them. The underlying spectral changes are …
color changes when switched between them. The underlying spectral changes are …
Understanding the origin of one-or two-step valence tautomeric transitions in bis (dioxolene)-bridged dinuclear cobalt complexes
Valence tautomerism (VT) involves a reversible stimulated intramolecular electron transfer
between a redox-active ligand and redox-active metal. Bis (dioxolene)-bridged dinuclear …
between a redox-active ligand and redox-active metal. Bis (dioxolene)-bridged dinuclear …
Controlling Spin Crossover in a Family of Dinuclear Fe (III) Complexes via the Bis (catecholate) Bridging Ligand
Spin crossover (SCO) complexes can reversibly switch between low spin (LS) and high spin
(HS) states, affording possible applications in sensing, displays, and molecular electronics …
(HS) states, affording possible applications in sensing, displays, and molecular electronics …
Modulation of Charge Distribution in Cobalt-α-Diimine Complexes toward Valence Tautomerism
Valence tautomerism (VT) and spin crossover (SCO) are promising avenues for develo**
a range of molecular materials for sensing, memory, and optoelectronic applications …
a range of molecular materials for sensing, memory, and optoelectronic applications …
Recent progress in the chemistry of 12-membered pyridine-containing tetraazamacrocycles: from synthesis to catalysis
This article provides an overview (non-comprehensive) of the recent developments
regarding pyridine-containing 12-membered tetraazamacrocycles with pyclen or Py2N2 …
regarding pyridine-containing 12-membered tetraazamacrocycles with pyclen or Py2N2 …
Tuning valence tautomerism in a family of dinuclear cobalt complexes incorporating a conjugated bridging bis (dioxolene) ligand with weak communication
Valence tautomerism (VT) involves the stimulated reversible intramolecular electron transfer
between a redox-active metal and ligand. Dinuclear cobalt complexes bridged by bis …
between a redox-active metal and ligand. Dinuclear cobalt complexes bridged by bis …
A convenient DFT-based strategy for predicting transition temperatures of valence tautomeric molecular switches
The ability to identify promising candidate switchable molecules computationally, prior to
synthesis, represents a considerable advance in the development of switchable molecular …
synthesis, represents a considerable advance in the development of switchable molecular …
Impact of Counteranion on Reversible Spin-State Switching in a Series of Cobalt (II) Complexes Containing a Redox-Active Ethylenedioxythiophene-Based …
The self-assembly of a redox-active ethylenedioxythiophene (EDOT)-terpyridine-based
tridentate ligand and cobalt (II) unit with different counteranions has led to a series of new …
tridentate ligand and cobalt (II) unit with different counteranions has led to a series of new …