Recent trends and fundamental insights in the methanol-to-hydrocarbons process
The production of high-demand chemical commodities such as ethylene and propylene
(methanol-to-olefins), hydrocarbons (methanol-to-hydrocarbons), gasoline (methanol-to …
(methanol-to-olefins), hydrocarbons (methanol-to-hydrocarbons), gasoline (methanol-to …
Carbocation chemistry confined in zeolites: spectroscopic and theoretical characterizations
Acid-catalyzed reactions inside zeolites are one type of broadly applied industrial reactions,
where carbocations are the most common intermediates of these reaction processes …
where carbocations are the most common intermediates of these reaction processes …
Aromatics production via methanol-mediated transformation routes
The methanol-to-aromatics (MTA) process is regarded as a promising route to produce
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …
Conversion of methanol to olefins over H-ZSM-5 zeolite: reaction pathway is related to the framework aluminum siting
T Liang, J Chen, Z Qin, J Li, P Wang, S Wang… - Acs …, 2016 - ACS Publications
As the conversion of methanol to olefins (MTO) over a zeolite catalyst is conducted on acid
sites derived from framework aluminum (AlF), it is possible to enhance the catalytic …
sites derived from framework aluminum (AlF), it is possible to enhance the catalytic …
Hydrogen transfer pathways during zeolite catalyzed methanol conversion to hydrocarbons
S Müller, Y Liu, FM Kirchberger… - Journal of the …, 2016 - ACS Publications
Hydrogen transfer is the major route in catalytic conversion of methanol to olefins (MTO) for
the formation of nonolefinic byproducts, including alkanes and aromatics. Two separate …
the formation of nonolefinic byproducts, including alkanes and aromatics. Two separate …
Selective introduction of acid sites in different confined positions in ZSM-5 and its catalytic implications
C Li, A Vidal-Moya, PJ Miguel, J Dedecek… - ACS …, 2018 - ACS Publications
Controlling the location of acid sites in zeolites can have a great effect on catalysis. In this
work we face the objective of directing the location of Al into the 10R channels of ZSM-5 by …
work we face the objective of directing the location of Al into the 10R channels of ZSM-5 by …
On reaction pathways in the conversion of methanol to hydrocarbons on HZSM-5
The underlying mechanisms of the two distinct catalytic cycles operating during conversion
of methanol to olefins (MTO) on HZSM-5 have been elucidated under industrially relevant …
of methanol to olefins (MTO) on HZSM-5 have been elucidated under industrially relevant …
Critical role of formaldehyde during methanol conversion to hydrocarbons
Formaldehyde is an important intermediate product in the catalytic conversion of methanol to
olefins (MTO). Here we show that formaldehyde is present during MTO with an average …
olefins (MTO). Here we show that formaldehyde is present during MTO with an average …
A mechanistic basis for the effects of crystallite size on light olefin selectivity in methanol-to-hydrocarbons conversion on MFI
Light olefin selectivity in methanol-to-hydrocarbons conversion on MFI increases with an
increase in crystallite size because intra-crystalline residence time of methylbenzenes …
increase in crystallite size because intra-crystalline residence time of methylbenzenes …
Evaluating the role of descriptor-and spectator-type reaction intermediates during the early phases of zeolite catalysis
The philosophy of “Ikigai”─ a reason for being─ could be extended to rationalize the role of
organic reaction intermediates in zeolite catalysis. Each reaction intermediate's ikigai is …
organic reaction intermediates in zeolite catalysis. Each reaction intermediate's ikigai is …