Recent trends and fundamental insights in the methanol-to-hydrocarbons process

I Yarulina, AD Chowdhury, F Meirer, BM Weckhuysen… - Nature Catalysis, 2018 - nature.com
The production of high-demand chemical commodities such as ethylene and propylene
(methanol-to-olefins), hydrocarbons (methanol-to-hydrocarbons), gasoline (methanol-to …

Carbocation chemistry confined in zeolites: spectroscopic and theoretical characterizations

W Chen, X Yi, Z Liu, X Tang, A Zheng - Chemical Society Reviews, 2022 - pubs.rsc.org
Acid-catalyzed reactions inside zeolites are one type of broadly applied industrial reactions,
where carbocations are the most common intermediates of these reaction processes …

Aromatics production via methanol-mediated transformation routes

T Li, T Shoinkhorova, J Gascon, J Ruiz-Martinez - ACS Catalysis, 2021 - ACS Publications
The methanol-to-aromatics (MTA) process is regarded as a promising route to produce
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …

Conversion of methanol to olefins over H-ZSM-5 zeolite: reaction pathway is related to the framework aluminum siting

T Liang, J Chen, Z Qin, J Li, P Wang, S Wang… - Acs …, 2016 - ACS Publications
As the conversion of methanol to olefins (MTO) over a zeolite catalyst is conducted on acid
sites derived from framework aluminum (AlF), it is possible to enhance the catalytic …

Hydrogen transfer pathways during zeolite catalyzed methanol conversion to hydrocarbons

S Müller, Y Liu, FM Kirchberger… - Journal of the …, 2016 - ACS Publications
Hydrogen transfer is the major route in catalytic conversion of methanol to olefins (MTO) for
the formation of nonolefinic byproducts, including alkanes and aromatics. Two separate …

Selective introduction of acid sites in different confined positions in ZSM-5 and its catalytic implications

C Li, A Vidal-Moya, PJ Miguel, J Dedecek… - ACS …, 2018 - ACS Publications
Controlling the location of acid sites in zeolites can have a great effect on catalysis. In this
work we face the objective of directing the location of Al into the 10R channels of ZSM-5 by …

On reaction pathways in the conversion of methanol to hydrocarbons on HZSM-5

X Sun, S Mueller, Y Liu, H Shi, GL Haller… - Journal of catalysis, 2014 - Elsevier
The underlying mechanisms of the two distinct catalytic cycles operating during conversion
of methanol to olefins (MTO) on HZSM-5 have been elucidated under industrially relevant …

Critical role of formaldehyde during methanol conversion to hydrocarbons

Y Liu, FM Kirchberger, S Müller, M Eder… - Nature …, 2019 - nature.com
Formaldehyde is an important intermediate product in the catalytic conversion of methanol to
olefins (MTO). Here we show that formaldehyde is present during MTO with an average …

A mechanistic basis for the effects of crystallite size on light olefin selectivity in methanol-to-hydrocarbons conversion on MFI

R Khare, D Millar, A Bhan - Journal of Catalysis, 2015 - Elsevier
Light olefin selectivity in methanol-to-hydrocarbons conversion on MFI increases with an
increase in crystallite size because intra-crystalline residence time of methylbenzenes …

Evaluating the role of descriptor-and spectator-type reaction intermediates during the early phases of zeolite catalysis

X Gong, Y Ye, AD Chowdhury - ACS Catalysis, 2022 - ACS Publications
The philosophy of “Ikigai”─ a reason for being─ could be extended to rationalize the role of
organic reaction intermediates in zeolite catalysis. Each reaction intermediate's ikigai is …