Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
reactions are widely performed during single and multistep synthesis. However, besides the …
Additive and Counterion Effects in Iron-Catalyzed Reactions Relevant to C–C Bond Formation
NJ Bakas, ML Neidig - ACS catalysis, 2021 - ACS Publications
The use of iron catalysts in carbon–carbon bond forming reactions is of interest as an
alternative to precious metal catalysts, offering reduced cost, lower toxicity, and different …
alternative to precious metal catalysts, offering reduced cost, lower toxicity, and different …
'In-water', nickel-catalyzed mild preparation of allylic amines employing alcohols: application to 'all-water'synthesis of pharmaceuticals
Reported here is a nanomicelle-enabled,'in-water', nickel-catalyzed allylic amination
reaction using allylic alcohols under mild conditions (in the absence of additives/bases …
reaction using allylic alcohols under mild conditions (in the absence of additives/bases …
N-Butylpyrrolidone (NBP) as a non-toxic substitute for NMP in iron-catalyzed C (sp 2)–C (sp 3) cross-coupling of aryl chlorides
E Bisz, M Koston, M Szostak - Green Chemistry, 2021 - pubs.rsc.org
Although iron catalyzed cross-coupling reactions show extraordinary promise in reducing
the environmental impact of more toxic and scarce transition metals, one of the main …
the environmental impact of more toxic and scarce transition metals, one of the main …
A Solely Fe‐Catalyzed Sonogashira‐Type Coupling of non‐Activated Secondary Alkyl Iodides with Terminal Alkynes
F Zhurkin, W Parisot, G Lefèvre - Advanced Synthesis & …, 2024 - Wiley Online Library
An iron‐catalyzed Sonogashira coupling of non‐activated secondary alkyl iodides with
terminal alkynes is described. The reaction proceeds under mild conditions in N …
terminal alkynes is described. The reaction proceeds under mild conditions in N …
The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts
The molecular-level role of alkoxide salts, used as alternative additive to N-
methylpyrrolidone in iron-catalyzed alkyl–alkenyl/aryl cross-coupling reactions, is …
methylpyrrolidone in iron-catalyzed alkyl–alkenyl/aryl cross-coupling reactions, is …
Iron-Catalyzed Carbon–Carbon Coupling Reaction
Q Zhang, SF Zhu - CC Cross Couplings with 3d Base Metal Catalysts, 2023 - Springer
Transition metal-catalyzed coupling reaction is one of the most effective strategies to
construct carbon–carbon bonds. Because iron is Earth abundant and environmental benign …
construct carbon–carbon bonds. Because iron is Earth abundant and environmental benign …
IBzH (IBenzhydryl): sterically-flexible N-aliphatic N-heterocyclic carbenes (NHCs) for iron-catalyzed C (sp 3)–C (sp 2) cross-coupling of unactivated haloalkanes
M Kardela, B Dziuk, R Szostak, M Szostak… - Catalysis Science & …, 2024 - pubs.rsc.org
Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable
products across various facets of chemical research, including pharmaceuticals, organic …
products across various facets of chemical research, including pharmaceuticals, organic …
Metal‐Free Transamidation of Primary Amides using Trimethylsilyl Chloride
S Yu, K Ho Song, S Lee - Asian Journal of Organic Chemistry, 2019 - Wiley Online Library
A metal‐free transamidation of primary amides was developed. Trimethylsilyl chloride
(TMSCl) acted as the activator in transamidation. In the presence of TMSCl, primary amides …
(TMSCl) acted as the activator in transamidation. In the presence of TMSCl, primary amides …
Advancing Sustainable Peptide Synthesis by Solvent Quality Control: Understanding and Mitigating Hydroperoxide in 1-Butyl-2-pyrrolidinone (NBP)
J Pawlas, TM El-Dine, K Bargen, C Bargen… - … Process Research & …, 2024 - ACS Publications
While numerous studies aimed at producing peptides in a sustainable manner have recently
been reported, the impact of the quality of starting materials on sustainability in peptide …
been reported, the impact of the quality of starting materials on sustainability in peptide …