Identifying photolysis and photothermolysis during a photochemical reaction has remained
challenging because of the highly non-equilibrium and ultrafast nature of the processes …

Intermediate states to covalent attachment of molecules on surfaces, so called precursors,
are usually considered to be physisorbed and mobile. We show that this view should be …

Controlling chemical reactions beyond thermally activated reaction schemes can open
alternative reaction channels, and thus lead to new final products. Herein, we show for …

Bond-selective reaction is central to heterogeneous catalysis. In heterogeneous catalysis,
selectivity is found to depend on the chemical nature and morphology of the substrate. Here …

We present first-principles molecular dynamics simulations of oxygen difluoride im**ing
upon the monohydrogenated Si {001}(2× 1) surface. Adsorption occurred in fewer than 10 …

The interaction of highly reactive species with solid surfaces can result in modes of
adsorption quite distinct from the classic molecular and dissociative events that are usually …

The electron-induced dissociation of chemisorbed HS to give recoiling H-atoms was
investigated on a Si (111)-7× 7 surface at 270 K by scanning tunnelling microscopy and …

Reaction dynamics of meta-diiodobenzene (mDIB) and trifluoromethyl (CF3) was studied on
the anisotropic Cu (110) surface at 4.6 K using Scanning Tunneling Microscopy (STM). Both …