Manganese (Mn) is a perfect candidate as catalyst in the sustainable organic
transformations. It is the second most abundant metal in earth's crust, inexpensive, and non …

The ubiquity of carbon halogen bonds in the structural core of numerous biomolecules and
pharmaceuticals along with their role as synthetic precursors in various organic reactions …

Abstract C (sp3)− Cl bonds are present in numerous biologically active small molecules, and
an ideal route for their preparation is by the chlorination of a C (sp3)− H bond. However …

Site-selective chlorination of benzylic C–H bonds is achieved using a CuICl/bis (oxazoline)
catalyst with N-fluorobenzenesulfonimide as the oxidant and KCl as a chloride source. This …

Strategies that enable intermolecular site-selective C–H bond functionalisation of organic
molecules provide one of the cornerstones of modern chemical synthesis. In chloroalkane …

Direct installation of key functionalities in a molecule through C− H bond activation is one of
the thrust areas as well as challenging task in organic synthesis. Particularly, introduction of …

Enzymes are most efficient catalyst for organic transformations including halogenation of C–
H bonds. Most of the halogenating enzymes utilize high valent metal-oxo intermediates for …

Here we report a light‐induced FeCl3‐catalyzed approach for benzyl C− H chlorination with
remarkable regioselectivity, which enables alkylbenzenes to be converted into versatile …

Non-heme iron complexes with cis-FeIII (OH)(SAr/OAr) coordination were isolated and
examined for their reactivity with a tertiary carbon radical. The sulfur-ligated complex shows …

Alkane functionalization using safe and low-energy processes is of great interest to industry
and academia. Aiming to contribute to the process of saturated hydrocarbon …