[HTML][HTML] From chemical gardens to chemobrionics

LM Barge, SSS Cardoso, JHE Cartwright… - Chemical …, 2015 - ACS Publications
Chemical gardens are perhaps the best example in chemistry of a self-organizing
nonequilibrium process that creates complex structures. Many different chemical systems …

Self-organization in precipitation reactions far from the equilibrium

E Nakouzi, O Steinbock - Science Advances, 2016 - science.org
Far from the thermodynamic equilibrium, many precipitation reactions create complex
product structures with fascinating features caused by their unusual origins. Unlike the …

CO2 reduction driven by a pH gradient

R Hudson, R de Graaf… - Proceedings of the …, 2020 - National Acad Sciences
All life on Earth is built of organic molecules, so the primordial sources of reduced carbon
remain a major open question in studies of the origin of life. A variant of the alkaline …

Metabolically diverse primordial microbial communities in Earth's oldest seafloor-hydrothermal jasper

D Papineau, Z She, MS Dodd, F Iacoviello, JF Slack… - Science …, 2022 - science.org
The oldest putative fossils occur as hematite filaments and tubes in jasper-carbonate
banded iron formations from the 4280-to 3750-Ma Nuvvuagittuq Supracrustal Belt, Québec …

A self-sustaining serpentinization mega-engine feeds the fougerite nanoengines implicated in the emergence of guided metabolism

MJ Russell - Frontiers in Microbiology, 2023 - frontiersin.org
The demonstration by Ivan Barnes et al. that the serpentinization of fresh Alpine-type
ultramafic rocks results in the exhalation of hot alkaline fluids is foundational to the …

Contrasting theories of life: Historical context, current theories. In search of an ideal theory

A Cornish-Bowden, ML Cárdenas - Biosystems, 2020 - Elsevier
Most attempts to define life have concentrated on individual theories, mentioning others
hardly at all, but here we compare all of the major current theories. We begin by asking how …

From chemical gardens to fuel cells: generation of electrical potential and current across self‐assembling iron mineral membranes

LM Barge, Y Abedian, MJ Russell… - Angewandte Chemie …, 2015 - Wiley Online Library
We examine the electrochemical gradients that form across chemical garden membranes
and investigate how self‐assembling, out‐of‐equilibrium inorganic precipitates—mimicking …

Hybrid organic–inorganic structures trigger the formation of primitive cell-like compartments

S Holler, S Bartlett, RJG Löffler… - Proceedings of the …, 2023 - National Acad Sciences
Alkaline hydrothermal vents have become a candidate setting for the origins of life on Earth
and beyond. This is due to several key features including the presence of gradients of …

Osmotic energy conversion in serpentinite-hosted deep-sea hydrothermal vents

HE Lee, T Okumura, H Ooka, K Adachi… - Nature …, 2024 - nature.com
Cells harvest energy from ionic gradients by selective ion transport across membranes, and
the same principle is recently being used for osmotic power generation from salinity …

Spiral precipitation patterns in confined chemical gardens

F Haudin, JHE Cartwright, F Brau… - Proceedings of the …, 2014 - National Acad Sciences
Chemical gardens are mineral aggregates that grow in three dimensions with plant-like
forms and share properties with self-assembled structures like nanoscale tubes, brinicles, or …