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Size-driven structural and thermodynamic complexity in iron oxides
A Navrotsky, L Mazeina, J Majzlan - Science, 2008 - science.org
Iron oxides occur ubiquitously in environmental, geological, planetary, and technological
settings. They exist in a rich variety of structures and hydration states. They are commonly …
settings. They exist in a rich variety of structures and hydration states. They are commonly …
Progress and new directions in calorimetry: A 2014 perspective
A Navrotsky - Journal of the American Ceramic Society, 2014 - Wiley Online Library
To assess progress in high‐temperature calorimetry over the past eighteen years, this
feature article discusses both technical developments and new areas of application, with …
feature article discusses both technical developments and new areas of application, with …
Energetics of nanocrystalline TiO2
The energetics of the TiO2 polymorphs (rutile, anatase, and brookite) were studied by high
temperature oxide melt drop solution calorimetry. Relative to bulk rutile, bulk brookite is …
temperature oxide melt drop solution calorimetry. Relative to bulk rutile, bulk brookite is …
Thermodynamics of guest-induced structural transitions in hybrid organic− inorganic frameworks
We provide a general thermodynamic framework for the understanding of guest-induced
structural transitions in hybrid organic− inorganic materials. The method is based on the …
structural transitions in hybrid organic− inorganic materials. The method is based on the …
Energy crossovers in nanocrystalline zirconia
The synthesis of nanocrystalline powders of zirconia often produces the tetragonal phase,
which for coarse‐grained powders is stable only at high temperatures and transforms into …
which for coarse‐grained powders is stable only at high temperatures and transforms into …
Thermochemistry of rare-earth orthophosphates
The enthalpies of formation for the compounds (RE3+) PO4,(where RE= Sc, Y, La–Nd, Sm–
Lu) were determined by oxide-melt solution calorimetry. Calorimetric measurements were …
Lu) were determined by oxide-melt solution calorimetry. Calorimetric measurements were …
Nanoscale effects on thermodynamics and phase equilibria in oxide systems
A Navrotsky - ChemPhysChem, 2011 - Wiley Online Library
Because different solid materials (phases) have different surface energies, equilibria among
them will be significantly affected by particle size. This Minireview summarizes experimental …
them will be significantly affected by particle size. This Minireview summarizes experimental …
Integrated circular economy model system for direct lithium extraction: from minerals to batteries utilizing aluminum hydroxide
Aluminum hydroxide, an abundant mineral found in nature, exists in four polymorphs:
gibbsite, bayerite, nordstrandite, and doyleite. Among these polymorphs gibbsite, bayerite …
gibbsite, bayerite, nordstrandite, and doyleite. Among these polymorphs gibbsite, bayerite …
Electrochemical analyses of redox-active iron minerals: a review of nonmediated and mediated approaches
Redox-active minerals are ubiquitous in the environment and are involved in numerous
electron transfer reactions that significantly affect biogeochemical processes and cycles as …
electron transfer reactions that significantly affect biogeochemical processes and cycles as …
Hierarchical materials as tailored nuclear waste forms: a perspective
This perspective focuses on the synthesis, characterization, and modeling of three classes of
hierarchical materials with potential for sequestering radionuclides: nanoparticles, porous …
hierarchical materials with potential for sequestering radionuclides: nanoparticles, porous …