An extensive survey of the occurrences and origins of both structural trans-effects (STEs)
and kinetic trans-effects (KTEs) in octahedral d-transition metal complexes is presented. This …

The chemistry of transition-metal-NO complexes, or metal nitrosyls, has taken on added
significance in recent years because of the important role that nitric oxide has been found to …

Chemistry of transition metal cyanide compounds: Modern perspectives Page 287
Chemistry of Transition Metal Cyanide Compounds: Modern Perspectives KIM R. DUNBAR …

Platinum-group metal halide-sulfoxide complexes, and dimethyl sulfoxide (dmso) complexes
in particular, have a rich chemistry and are widely used as precursors in inorganic synthesis …

Some 20 years ago, I was privileged to share in writing a book on the descriptive chemistry
of the 4d, 5d, 4f and 5f metals that included these eight elements within its compass (SA …

The factors that explain the competition between intramolecular NO linkage
photoisomerization and NO photorelease in five ruthenium nitrosyl complexes were …

The N→ O linkage photoisomerization mechanism in a ruthenium nitrosyl complex,[RuCl
(NO)(py) 4] 2+, for which a quasicomplete photoconversion between the stable nitrosyl (N …

Two light-induced metastable NO linkage isomers with oxygen-bound (SI) and side-on
configuration (SII) of NO are generated in trans-[RuCl (py) 4 (NO)][PF6] 2· ½H2O. Irradiation …

The density functional theory calculations presented in this work allow the first rationalization
of the full linkage photoisomerization mechanism of trans-[RuCl (NO)(py) 4] 2+, in both the …

The design of photoswitchable transition metal complexes with tailored properties is one of
the most important challenges in chemistry. Studies explaining the underlying mechanisms …