Understanding the unceasing evolution of Co (II) based single-ion magnets
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …
Single ion magnets from 3d to 5f: developments and strategies
M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?
Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …
Probing the effect of axial ligands on easy-plane anisotropy of pentagonal-bipyramidal cobalt (II) single-ion magnets
We herein reported the synthetic, structural, computational, and magnetic studies of four air-
stable heptacoordinated mononuclear cobalt (II) complexes, namely,[CoII (tdmmb)(H2O) …
stable heptacoordinated mononuclear cobalt (II) complexes, namely,[CoII (tdmmb)(H2O) …
Co (II) single-ion magnets: synthesis, structure, and magnetic properties
J Juráková, I Šalitroš - Monatshefte für Chemie-Chemical Monthly, 2022 - Springer
Magnetoactive coordination compounds exhibiting bi-or multistability between two or more
magnetic stable states present an attractive example of molecular switches. Currently, the …
magnetic stable states present an attractive example of molecular switches. Currently, the …
Relaxation dynamics of identical trigonal bipyramidal Cobalt molecules with different local symmetries and packing arrangements: Magnetostructural correlations and …
TJ Woods, MF Ballesteros-Rivas… - Journal of the …, 2016 - ACS Publications
A family of isostructural, mononuclear CoII complexes with distorted trigonal bipyramidal
coordination environments is reported. The degree of distortion as well as the overall …
coordination environments is reported. The degree of distortion as well as the overall …
Pseudo‐Contact NMR Shifts over the Paramagnetic Metalloprotein CoMMP‐12 from First Principles
Long‐range pseudo‐contact NMR shifts (PCSs) provide important restraints for the structure
refinement of proteins when a paramagnetic metal center is present, either naturally or …
refinement of proteins when a paramagnetic metal center is present, either naturally or …
Probing the effects of ligand field and coordination geometry on magnetic anisotropy of pentacoordinate Cobalt (II) single-ion magnets
In this work, the effects of ligand field strength as well as the metal coordination geometry on
magnetic anisotropy of pentacoordinated CoII complexes have been investigated using a …
magnetic anisotropy of pentacoordinated CoII complexes have been investigated using a …
Ultra-broadband EPR spectroscopy in field and frequency domains
P Neugebauer, D Bloos, R Marx, P Lutz… - Physical Chemistry …, 2018 - pubs.rsc.org
Electron paramagnetic resonance (EPR) is a powerful technique to investigate the electronic
and magnetic properties of a wide range of materials. We present the first combined …
and magnetic properties of a wide range of materials. We present the first combined …
Late first-row transition-metal complexes containing a 2-pyridylmethyl pendant-armed 15-membered macrocyclic ligand. Field-induced slow magnetic relaxation in a …
The 2-pyridylmethyl N-pendant-armed heptadentate macrocyclic ligand {3, 12-bis (2-
methylpyridine)-3, 12, 18-triaza-6, 9-dioxabicyclo [12.3. 1] octadeca-1, 14, 16-triene= L} and …
methylpyridine)-3, 12, 18-triaza-6, 9-dioxabicyclo [12.3. 1] octadeca-1, 14, 16-triene= L} and …