Palladium (II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines

Y Huang, SA Pullarkat, Y Li, PH Leung - Chemical communications, 2010 - pubs.rsc.org
Palladium(ii) -catalyzed asymmetric hydrophosphination of enones : efficient access to chiral
tertiary phosphines - Chemical Communications (RSC Publishing) DOI:10.1039/C0CC00925C …

Phosphines and related C–P bonded compounds

DW Allen - 2015 - books.rsc.org
This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …

Palladacycle-catalyzed asymmetric intermolecular construction of chiral tertiary P-heterocycles by stepwise addition of H–P–H bonds to bis (enones)

Y Huang, SA Pullarkat, S Teong, RJ Chew, Y Li… - …, 2012 - ACS Publications
A palladacycle-catalyzed diastereo-and enantioselective stepwise double
hydrophosphination of bis (enones) with PhPH2 has been developed, allowing …

Chiral metal complex-promoted asymmetric hydrophosphinations

SA Pullarkat, PH Leung - Hydrofunctionalization, 2013 - Springer
This chapter provides an account of the synthesis of a series of chiral tertiary phosphines via
the metal complex-assisted asymmetric hydrophosphination methodology which involves …

Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters: direct access to functionalized …

C Xu, G Jun Hao Kennard, F Hennersdorf, Y Li… - …, 2012 - ACS Publications
A chiral palladacycle-promoted enantioselective asymmetric hydrophosphination of
substituted methylidenemalonate esters using diphenylphosphine that provides direct …

Highly enantioselective synthesis of (2-pyridyl) phosphine based C-chiral unsymmetrical P, N-ligands using a chiral palladium complex

F Liu, SA Pullarkat, Y Li, S Chen, M Yuan, ZY Lee… - …, 2009 - ACS Publications
The organopalladium complex containing ortho-metalated (R)-(1-(dimethylamino) ethyl)
naphthalene as the chiral auxiliary has been used to promote the asymmetric …

Post-metallation functionalization of the [(C^ C) Au (P^ P)]+ scaffold through a hydrothiolation reaction

J Yang, C Soep, J Forté, H Dossmann… - Dalton Transactions, 2024 - pubs.rsc.org
Complex 1 [(C^ C) Au (dppv)] PF6 (dppv= cis-1, 2-diphenylphosphinoethylene) is reported
to react efficiently and selectively with aliphatic and aromatic thiols in the presence of a …

Optically active macrocyclic hexaazapyridinophanes decorated at the periphery: synthesis and applications in the NMR enantiodiscrimination of carboxylic acids

E Busto, A González-Álvarez, V Gotor-Fernández… - Tetrahedron, 2010 - Elsevier
A family of pyridine based dialdehydes has been efficiently prepared starting from
chelidamic acid by chemical modification of its 4-hydroxyl group. The condensation of these …

Stereoelectronic and catalytic properties of chiral cyclometalated phospha-palladium and-platinum complexes

YX Jia, BB Li, Y Li, SA Pullarkat, K Xu, H Hirao… - …, 2014 - ACS Publications
The stereoelectronic properties of palladium (II) and platinum (II) complexes containing ortho-
metalated (1-(diphenylphosphino) ethyl) naphthalene were examined by X-ray …

Asymmetric synthesis of new diphosphines and pyridylphosphines via a kinetic resolution process promoted and controlled by a chiral palladacycle

S Chen, JKP Ng, SA Pullarkat, F Liu, Y Li… - …, 2010 - ACS Publications
A chiral palladacycle has been used successfully to promote the asymmetric
hydrophosphination reactions between the racemic secondary phosphine …