Phenols are widely used as starting materials in both industrial and academic society.
Dearomatization reactions of phenols provide an efficient way to construct highly …

This Review summarizes the development of catalytic asymmetric dearomatization (CADA)
reactions. The CADA reactions discussed herein include oxidative dearomatization …

Cross-coupling reactions, which were discovered almost 50 years ago, are widely used in
both industry and academia. Even though cross-coupling reactions now represent mature …

The catalytic enantioselective assembly of spirocyclic molecules featuring a spiro quaternary
carbon stereocenter is currently of great interest because such privileged 3D structures are …

An enantioselective C− H arylation of phosphine oxides with o‐quinone diazides catalyzed
by an iridium (III) complex bearing an atropchiral cyclopentadienyl (Cpx) ligand and …

Chiral Brønsted acid-catalysed asymmetric synthesis has received tremendous interest over
the past decades, and numerous efficient synthetic methods have been developed based on …

Conspectus Dearomatization reactions serve as powerful methods for the synthesis of highly
functionalized, three-dimensional structures starting with simple planar aromatic …

Covering: 2013–2018 Natural products bearing quaternary carbon stereocenters have
attracted tremendous interest from the synthetic community due to their diverse biological …

This review summarizes the recent advances in the field of asymmetric dearomatization of
phenols and their applications in the total synthesis of some complex natural products. The …

Phenols are important starting materials, intermediates, and functional elements of a very
broad range of chemicals and materials. They are large-volume products of benzene …