C (sp2)–C (sp3) bonds comprise the fundamental skeletons of many organic molecules,
making their construction one of the most important transformations in synthetic chemistry …

Currently, photoreactions have become powerful synthetic tools with a broad scope of
application. However, many photoreactions require the addition of transition-metal catalysts …

Hydrogen atom abstraction (HAT) from C (sp 3)–H bonds of naturally abundant alkanes for
alkyl radical generation represents a promising yet underexplored strategy in the alkylation …

Visible-light-driven organic photochemical reactions have attracted substantial attention
from the synthetic community. Typically, catalytic quantities of photosensitizers, such as …

Minisci alkylation is of prime importance for its applicability in functionalizing diverse
heteroarenes, which are core structures in many bioactive compounds. In alkyl radical …

The sustainable cross-dehydrogenative coupling of strong C (sp3)–H with N-heteroarenes
has been developed using an efficient organic photocatalyst. It features atomic-and step …

Designing molecular photocatalysts for potent photochemical reactivities ranks among the
most challenging but rewarding endeavors in synthetic photochemistry. Herein, we …

Radical cleavage of C–B bonds to accomplish C–H functionalization is synthetically
appealing but practically challenging. We report herein a mild electro-oxidative method for …

The intermolecular radical addition to the carbonyl group is difficult due to the facile
fragmentation of the resulting alkoxyl radical. To date, the intermolecular radical addition to …

Photoinduced transition-metal-and photosensitizer-free cross-coupling of aryl halides
(including Ar–Cl, Ar–Br, and Ar–I) with H-phosphonates (including dialkyl phosphonates and …