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Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
'Catalyst+ X'strategies for transition metal-catalyzed olefin-polar monomer copolymerization
Transition metal-catalyzed olefin-polar monomer copolymerization holds great potential for
the synthesis of polar group-functionalized polyolefin materials. The dominant approach to …
the synthesis of polar group-functionalized polyolefin materials. The dominant approach to …
A general strategy for heterogenizing olefin polymerization catalysts and the synthesis of polyolefins and composites
The heterogenization of homogeneous metal complexes on solid supports presents an
efficient strategy for bridging homogeneous catalysts with industrially-preferred …
efficient strategy for bridging homogeneous catalysts with industrially-preferred …
Rapid atom-efficient polyolefin plastics hydrogenolysis mediated by a well-defined single-site electrophilic/cationic organo-zirconium catalyst
Polyolefins comprise a major fraction of single-use plastics, yet their catalytic deconstruction/
recycling has proven challenging due to their inert saturated hydrocarbon connectivities …
recycling has proven challenging due to their inert saturated hydrocarbon connectivities …
Synthesis of polar-functionalized isotactic polypropylenes using commercial heterogeneous Ziegler–Natta catalyst
The efficient synthesis of polar-functionalized polypropylenes with high molecular weight
and high stereoregularity represents a challenging task. This challenge becomes even more …
and high stereoregularity represents a challenging task. This challenge becomes even more …
An ionic cluster strategy for performance improvements and product morphology control in metal-catalyzed olefin–polar monomer copolymerization
Product morphology control represents a critical challenge for polyolefin production, but it
has remained largely unexplored in the field of ethylene–polar monomer copolymerization …
has remained largely unexplored in the field of ethylene–polar monomer copolymerization …
A co-anchoring strategy for the synthesis of polar bimodal polyethylene
Since polar groups can poison the metal centers in catalysts, the incorporation of polar
comonomers usually comes at the expense of catalytic activity and polymer molecular …
comonomers usually comes at the expense of catalytic activity and polymer molecular …
Outer‐shell self‐supported nickel catalysts for the synthesis of polyolefin composites
In situ heterogeneous olefin polymerization has attracted much attention for the synthesis of
polyolefin composites. However, the complicated syntheses of specially designed catalysts …
polyolefin composites. However, the complicated syntheses of specially designed catalysts …
Hydrogen‐bonding‐induced heterogenization of nickel and palladium catalysts for copolymerization of ethylene with polar monomers
The practical synthesis of polar‐functionalized polyolefins using transition‐metal‐catalyzed
copolymerization of olefins with polar monomers is a challenge; the use of heterogeneous …
copolymerization of olefins with polar monomers is a challenge; the use of heterogeneous …
Heterogenization strategies for nickel catalyzed synthesis of polyolefins and composites
Conspectus Polyolefin is one of the most common synthetic polymers. However, most
polyolefins are nonpolar materials, which leads to poor compatibility with polar materials …
polyolefins are nonpolar materials, which leads to poor compatibility with polar materials …