The geometry at an element centre can generally be predicted based on the number of
electron pairs around it using valence shell electron pair repulsion (VSEPR) theory …

Since the prediction of the existence of metallabenzenes in 1979, metallaaromatic chemistry
has developed rapidly, due to its importance in both experimental and theoretical fields …

Low-work-function (WF) metals (including silver (Ag), aluminum (Al), and copper (Cu)) used
as external cathodes in inverted perovskite solar cells (PSCs) encounter oxidation caused …

Conspectus Aromatic compounds are important in synthetic chemistry, biomedicines, and
materials science. As a special type of aromatic complex, transition-metal-based …

Heterogeneous single‐metal‐site catalysts (SMSCs), often referred to as single‐atom
catalysts (SACs), demonstrate promising catalytic activity, selectivity, and stability across a …

Due to its built-up chemoresistance after prolonged usage, the demand for replacing
platinum in metal-based drugs (MBD) is rising. The first MBD approved by the FDA for …

The structural design and tuning of properties of metallaaromatics are crucial in materials
and energy science. Herein, we describe the rapid synthesis of tetracyclic metallaaromatics …

The first rhena-analogues of pyridinium (cyclopropametalla-2-isoquinolinium complexes)
are obtained from o-ethynyl benzonitriles. Structural analysis and DFT calculations confirm …

Metal-containing polymers have drawn considerable interest because of their unexpected
and fantastic properties, and can be applied for preparing functional hydrogels. However …

A convenient synthetic route to polycyclic metallaaromatics containing main-group
heteroatoms has been developed. The first cyclopropametalla-2-benzopyrylium complexes …