The enzyme carbonic anhydrase has been intensely studied over decades as a means to
understand the role of zinc in hydrating CO2. The naturally occurring enzyme has also been …

Reported are the synthesis and detailed studies of the iron (IV)-tosylimido complexes of two
isomeric pentadentate bispidine ligands (bispidines are 3, 7-diazabicyclo [3.3. 1] nonane …

Real-time monitoring of the lysosomal microenvironment using small-molecule probes is
critical for understanding the complex interactions between organelles and diseases …

In copper-based enzymes, Cu-hydroperoxo/alkylperoxo species are proposed as key
intermediates for their biological activity. A vast amount of literature is available on the …

The first-coordination sphere of catalysts is known to play a crucial role in reaction
mechanisms, but details of how equatorial ligands influence the reactivity remain unknown …

While the oxidation of organic substrates by FeIV‐oxido complexes has been studied
extensively, there are only few highly reactive FeIII‐alkylperoxido complexes. We report here …