A review on modeling cure kinetics and mechanisms of photopolymerization

M Lang, S Hirner, F Wiesbrock, P Fuchs - Polymers, 2022 - mdpi.com
Photopolymerizations, in which the initiation of a chemical-physical reaction occurs by the
exposure of photosensitive monomers to a high-intensity light source, have become a well …

Laser-based additively manufactured polymers: a review on processes and mechanical models

R Brighenti, MP Cosma, L Marsavina… - Journal of Materials …, 2021 - Springer
Additive manufacturing (AM) is a broad definition of various techniques to produce layer-by-
layer objects made of different materials. In this paper, a comprehensive review of laser …

Molecularly imprinted polymers as the epitome of excellence in multiple fields

Y Han, J Tao, N Ali, A Khan, S Malik, H Khan… - European Polymer …, 2022 - Elsevier
Molecularly imprinted polymers (MIPs) are promising receptors for a wide range of targeted
molecules. In recent years, the construction of low molecular weight materials became …

Curing kinetic analysis of acrylate photopolymer for additive manufacturing by photo-DSC

F Jiang, D Drummer - Polymers, 2020 - mdpi.com
In this research, the curing degree of an acrylate-based monomer using direct UV-assisted
writing technology was characterized by differential photo calorimetry (Photo-DSC) to …

Modeling the kinetics, curing depth, and efficacy of radical-mediated photopolymerization: the role of oxygen inhibition, viscosity, and dynamic light intensity

JT Lin, HW Liu, KT Chen, DC Cheng - Frontiers in Chemistry, 2019 - frontiersin.org
Kinetic equations for a modeling system with type-I radical-mediated and type-II oxygen-
mediated pathways are derived and numerically solved for the photopolymerization efficacy …

Coumarin derivatives as photoinitiators in photo-oxidation and photo-reduction processes and a kinetic model for simulations of the associated polymerization profiles

M Abdallah, A Hijazi, JT Lin, B Graff… - ACS Applied Polymer …, 2020 - ACS Publications
In this work, the design of an original series of coumarin derivatives (CoumC1–CoumC13) is
presented. Chemical structures of these coumarins were selected by molecular modeling to …

Efficacy modeling of new multi-functional benzophenone-based system for free-radical/cationic hybrid-photopolymerization using 405 nm LED

JT Lin, YZ Lee, J Lalevee - Journal of Polymer Research, 2022 - Springer
This article presents, for the first time, the kinetics and the general conversion features of a 3-
component system, benzophenone–triphenylamine (BT)/iodonium/Amine, based on …

Efficacy analysis of new copper complex for visible light (455, 530 nm) radical/cationic photopolymerization: The synergic effects and catalytic cycle

JT Lin, J Lalevee, DC Cheng - Plos one, 2022 - journals.plos.org
The kinetics and the conversion features of two 3-component systems (A/B/N), based on the
proposed new kinetic schemes of Mokbel and Mau et al, in which a visible LED is used to …

Dual-wavelength (UV and blue) controlled photopolymerization confinement for 3D-printing: Modeling and analysis of measurements

JT Lin, DC Cheng, KT Chen, HW Liu - Polymers, 2019 - mdpi.com
The kinetics and modeling of dual-wavelength (UV and blue) controlled photopolymerization
confinement (PC) are presented and measured data are analyzed by analytic formulas and …

Ultra-high through-cure of (meth) acrylate copolymers via photofrontal polymerization

C Ebner, J Mitterer, P Eigruber, S Stieger, G Riess… - Polymers, 2020 - mdpi.com
Photopolymerization offers substantial advantages in terms of time, temperature, energy
consumption, and spatial control of the initiation. The application however is strongly limited …