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[HTML][HTML] Pressure-induced phase transitions in sesquioxides
Pressure is an important thermodynamic parameter, allowing the increase of matter density
by reducing interatomic distances that result in a change of interatomic interactions. In this …
by reducing interatomic distances that result in a change of interatomic interactions. In this …
Noble gases in solid compounds show a rich display of chemistry with enough pressure
M Miao - Frontiers in Chemistry, 2020 - frontiersin.org
In this review, we summarize the rapid progress that has been made in the study of noble
gas chemistry in solid compounds under high pressure. Thanks to the recent development of …
gas chemistry in solid compounds under high pressure. Thanks to the recent development of …
Tracking structural phase transitions via single crystal X-ray diffraction at extreme conditions: advantages of extremely brilliant source
Highly brilliant synchrotron source is indispensable to track pressure-induced phenomena in
confined crystalline samples in megabar range. In this article, a number of experimental …
confined crystalline samples in megabar range. In this article, a number of experimental …
[HTML][HTML] Lab in a DAC–high-pressure crystal chemistry in a diamond-anvil cell
A Katrusiak - Structural Science, 2019 - journals.iucr.org
The diamond-anvil cell (DAC) was invented 60 years ago, ushering in a new era for material
sciences, extending research into the dimension of pressure. Most structural determinations …
sciences, extending research into the dimension of pressure. Most structural determinations …
Disorder–order transitions in the perovskite metal–organic frameworks [(CH 3) 2 NH 2][M (HCOO) 3] at high pressure
High-pressure single-crystal X-ray diffraction was performed on dimethylammonium metal
formates (DMAMF),[(CH3) 2NH2][M (HCOO) 3] where M= Mn2+, Fe2+, and Cu2+, in order to …
formates (DMAMF),[(CH3) 2NH2][M (HCOO) 3] where M= Mn2+, Fe2+, and Cu2+, in order to …
Synthesis and Properties of the Helium Clathrate and Defect Perovskite [He2–x□x][CaNb]F6
S Ma, BR Hester, AJ Lloyd… - The Journal of …, 2024 - ACS Publications
The defect double perovskite [He2–x□ x][CaNb] F6, with helium on its A-site, can be
prepared by the insertion of helium into ReO3-type CaNbF6 at high pressure. Upon cooling …
prepared by the insertion of helium into ReO3-type CaNbF6 at high pressure. Upon cooling …
High-pressure polymorphism in l-threonine between ambient pressure and 22 GPa
The crystal structure of L-threonine has been studied to a maximum pressure of 22.3 GPa
using single-crystal X-ray and neutron powder diffraction. The data have been interpreted in …
using single-crystal X-ray and neutron powder diffraction. The data have been interpreted in …
Hybrid Double Perovskite Containing Helium: [He2][CaZr]F6
AJ Lloyd, BR Hester, SJ Baxter, S Ma… - Chemistry of …, 2021 - ACS Publications
Perovskites are of great technological and geological importance, in large part, due to their
considerable compositional and structural flexibility. However, the formation of perovskites …
considerable compositional and structural flexibility. However, the formation of perovskites …
Demonstration of Helide formation for fusion structural materials as natural lattice sinks for helium
Fusion power holds promise as an ultimate energy source. However, achieving true
sustainability in fusion energy requires addressing the embrittlement of polycrystalline …
sustainability in fusion energy requires addressing the embrittlement of polycrystalline …
Intercalating Helium into A-Site Vacant Perovskites
Evolutionary searches were employed to predict the most stable structures of perovskites
with helium atoms on their A-sites up to a pressure of 10 GPa. The thermodynamics …
with helium atoms on their A-sites up to a pressure of 10 GPa. The thermodynamics …