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Observation of a promethium complex in solution
Lanthanide rare-earth metals are ubiquitous in modern technologies,,,–, but we know little
about chemistry of the 61st element, promethium (Pm), a lanthanide that is highly radioactive …
about chemistry of the 61st element, promethium (Pm), a lanthanide that is highly radioactive …
Aqueous interfaces in chemical separations
Chemical separations play a vital role in refinery and reprocessing of critical materials, such
as platinum group metals, rare earths, and actinides. The choice of separation system─ …
as platinum group metals, rare earths, and actinides. The choice of separation system─ …
We Already Know Everything about Oxidative Addition to Pd (0): Do We?
The oxidative addition (OA) of organic electrophiles to Pd (0) is a fundamental step in
organopalladium chemistry and plays a key role in palladium-catalyzed cross-coupling …
organopalladium chemistry and plays a key role in palladium-catalyzed cross-coupling …
Lanthanide Contraction: What is Normal?
RB Jordan - Inorganic Chemistry, 2023 - ACS Publications
Renewed interest in lanthanide contraction results from its possible effect on the properties
and applications of Ln (III) compounds and the theory related to these issues. To understand …
and applications of Ln (III) compounds and the theory related to these issues. To understand …
A Metal‐Organic Framework Incorporating Eight Different Size Rare‐Earth Metal Elements: Toward Multifunctionality À La Carte
Multi‐metallic multivariate (MTV) rare earth (RE) metal− organic frameworks (MOFs) are of
interest for the development of multifunctional materials, however examples with more than …
interest for the development of multifunctional materials, however examples with more than …
Evaluation of Point Group Symmetry in Lanthanide (III) Complexes: A New Implementation of a Continuous Symmetry Operation Measure with Autonomous …
The structure of molecular systems dictates the physical properties, and symmetry is the
determining factor for all electronic properties. This makes group theory a powerful tool in …
determining factor for all electronic properties. This makes group theory a powerful tool in …
A holistic approach for elucidating local structure, dynamics, and speciation in molten salts with high structural disorder
To examine ion solvation, exchange, and speciation for minority components in molten salts
(MS) typically found as corrosion products, we propose a multimodal approach combining …
(MS) typically found as corrosion products, we propose a multimodal approach combining …
Aqueous Structure of Lanthanide–EDTA Coordination Complexes Determined by a Combined DFT/EXAFS Approach
Sustainable production of rare earth elements (REEs) is critical for technologies needed for
climate change mitigation, including wind turbines and electric vehicles. However …
climate change mitigation, including wind turbines and electric vehicles. However …
[HTML][HTML] Solvent extraction in non-ideal eutectic solvents–Application towards lanthanide separation
Hydrophobic eutectic solvents (HES) emerged as promising substitutes to the conventional
organic phase used in the solvent extraction (SX) of metal ions due to the avoidance of …
organic phase used in the solvent extraction (SX) of metal ions due to the avoidance of …
Structures of Th 4+ aqueous solutions: insights from AIMD and metadynamics simulations
Solution chemistry of actinide ions is critical to understanding the solvation behaviors and
hydrolysis process. Using tetravalent thorium ion Th4+ as a representative example, we …
hydrolysis process. Using tetravalent thorium ion Th4+ as a representative example, we …