Electrochemistry under confinement

M Jaugstetter, N Blanc, M Kratz… - Chemical Society Reviews, 2022 - pubs.rsc.org
Although the term 'confinement'regularly appears in electrochemical literature, elevated by
continuous progression in the research of nanomaterials and nanostructures, up until today …

The birth and evolution of solvated electrons in the water

F Novelli, K Chen, A Buchmann… - Proceedings of the …, 2023 - National Acad Sciences
The photo-induced radiolysis of water is an elementary reaction in biology and chemistry,
forming solvated electrons, OH radicals, and hydronium cations on fast time scales. Here …

Terahertz spectrum of water at varying temperatures from 260 to 340 K: Contributions from permanent and induced dipole correlations at different length scales

D Sharma, B Das, A Chandra - The Journal of Physical Chemistry …, 2023 - ACS Publications
The terahertz (THz) absorption spectrum of water is calculated at varying temperatures from
260 to 340 K from molecular dynamics simulations using a polarizable potential model of …

Nanoconfinement effects on water in narrow graphene-based slit pores as revealed by THz spectroscopy

S Ruiz-Barragan, F Sebastiani, P Schienbein… - Physical Chemistry …, 2022 - pubs.rsc.org
The properties of water at interfaces have long been known to differ from those of bulk water
in many distinctive ways. More recently, specific confinement effects different from mere …

Towards intense THz spectroscopy on water: Characterization of optical rectification by GaP, OH1, and DSTMS at OPA wavelengths

F Novelli, B Guchhait, M Havenith - Materials, 2020 - mdpi.com
Water is the most prominent solvent. The unique properties of water are rooted in the
dynamical hydrogen-bonded network. While TeraHertz (THz) radiation can probe directly …

Strong anisotropy in liquid water upon librational excitation using terahertz laser fields

F Novelli, L Ruiz Pestana, KC Bennett… - The Journal of …, 2020 - ACS Publications
Tracking the excitation of water molecules in the homogeneous liquid is challenging due to
the ultrafast dissipation of rotational excitation energy through the hydrogen-bonded …

Ion-specific adsorption on bare gold (Au) nanoparticles in aqueous solutions: Double-layer structure and surface potentials

Z Li, VG Ruiz, M Kanduc, J Dzubiella - Langmuir, 2020 - ACS Publications
We study the solvation and electrostatic properties of bare gold (Au) nanoparticles (NPs) of 1–
2 nm in size in aqueous electrolyte solutions of sodium salts of various anions with large …

Universality in the Structure and Dynamics of Water under Lipidic Mesophase Soft Nanoconfinement

E Zunzunegui-Bru, SR Alfarano, P Zueblin… - ACS …, 2024 - ACS Publications
Water under soft nanoconfinement features physical and chemical properties fundamentally
different from bulk water; yet, the multitude and specificity of confining systems and …

Highly heterogeneous polarization and solvation of gold nanoparticles in aqueous electrolytes

Z Li, VG Ruiz, M Kanduc, J Dzubiella - ACS nano, 2021 - ACS Publications
The performance of gold nanoparticles (NPs) in applications depends critically on the
structure of the NP–solvent interface, at which the electrostatic surface polarization is one of …

Solvation of Nanoscale Materials

AN Mapile, E Svensson Grape… - Chemistry of …, 2024 - ACS Publications
The utility of colloidal nanomaterials in energy storage devices, high-definition displays, and
industrial coatings depends on their solution processability and stability. Traditional theories …