Metal-catalyzed Markovnikov-type selective hydrofunctionalization of terminal alkynes

J Chen, WT Wei, Z Li, Z Lu - Chemical Society Reviews, 2024 - pubs.rsc.org
Metal-catalyzed highly Markovnikov-type selective hydrofunctionalization of terminal alkynes
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …

On inventing reactions for atom economy

BM Trost - Accounts of chemical research, 2002 - ACS Publications
An important first step in making organic reactions more environmentally benign by design
requires processes that are, to a first approximation, simple additions with anything else …

Ruthenium‐catalyzed reactions—a treasure trove of atom‐economic transformations

BM Trost, MU Frederiksen… - Angewandte Chemie …, 2005 - Wiley Online Library
The demand for new chemicals spanning the fields of health care to materials science
combined with the pressure to produce these substances in an environmentally benign …

Visible‐Light‐Enabled Stereodivergent Synthesis of E‐ and Z‐Configured 1,4‐Dienes by Photoredox/Nickel Dual Catalysis

F Song, F Wang, L Guo, X Feng… - Angewandte Chemie …, 2020 - Wiley Online Library
A stereodivergent reductive coupling reaction between allylic carbonates and vinyl triflates
to furnish both E‐and Z‐configured 1, 4‐dienes has been achieved by visible‐light‐induced …

Catalytic anti-Markovnikov hydroallylation of terminal and functionalized internal alkynes: synthesis of skipped dienes and trisubstituted alkenes

M Mailig, A Hazra, MK Armstrong… - Journal of the American …, 2017 - ACS Publications
We have developed catalytic anti-Markovnikov hydroallylation of terminal and functionalized
internal alkynes. In this article, we describe the development of the reaction, exploration of …

Cobalt-catalyzed branched selective hydroallylation of terminal alkynes

J Chen, J Ying, Z Lu - Nature Communications, 2022 - nature.com
Here, we reported a cobalt-hydride-catalyzed Markovnikov-type hydroallylation of terminal
alkynes with allylic electrophile to access valuable and branched skipped dienes (1, 4 …

Nickel-catalyzed Heck-type reactions of benzyl chlorides and simple olefins

R Matsubara, AC Gutierrez… - Journal of the American …, 2011 - ACS Publications
Nickel-catalyzed intermolecular benzylation and heterobenzylation of unactivated alkenes to
provide functionalized allylbenzene derivatives are described. A wide range of both the …

A Convenient Synthetic Route to [CpRu(CH3CN)3]PF6

BM Trost, CM Older - Organometallics, 2002 - ACS Publications
A Convenient Synthetic Route to [CpRu(CH3CN)3]PF6 | Organometallics Recently Viewed
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Regio-and stereoselective divergent cross-coupling of alkynes and disubstituted alkenes via photoredox cobalt dual catalysis

SQ Zhang, YL Li, K Cui, C Chen, ZY Gu… - Organic Chemistry …, 2023 - pubs.rsc.org
Achieving divergent synthesis from the same substrates quickly to generate different
products remains an attractive objective in synthetic chemistry and the medicinal industry …

Ruthenium-catalyzed cycloisomerizations of diynols

BM Trost, MT Rudd - Journal of the American Chemical Society, 2005 - ACS Publications
A wide variety of diynols containing tertiary, secondary, and primary propargylic alcohols
undergo a cycloisomerization reaction to form dienones and dienals in the presence of a …