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Two-dimensional polymers and polymerizations
Synthetic chemists have developed robust methods to synthesize discrete molecules, linear
and branched polymers, and disordered cross-linked networks. However, two-dimensional …
and branched polymers, and disordered cross-linked networks. However, two-dimensional …
Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …
creating new organic materials. A large number of chemical reactions have been …
Covalent on-surface polymerization
With the rapid development of scanning probe microscopy, it has become possible to study
polymerization processes on suitable surfaces at the atomic level and in real space. In the …
polymerization processes on suitable surfaces at the atomic level and in real space. In the …
On‐Surface Synthesis of Carbon Nanostructures
Novel carbon nanomaterials have aroused significant interest owing to their prospects in
various technological applications. The recently developed on‐surface synthesis strategy …
various technological applications. The recently developed on‐surface synthesis strategy …
From graphene nanoribbons on Cu (111) to nanographene on Cu (110): critical role of substrate structure in the bottom-up fabrication strategy
Bottom-up strategies can be effectively implemented for the fabrication of atomically precise
graphene nanoribbons. Recently, using 10, 10′-dibromo-9, 9′-bianthracene (DBBA) as a …
graphene nanoribbons. Recently, using 10, 10′-dibromo-9, 9′-bianthracene (DBBA) as a …
From helical to planar chirality by on-surface chemistry
The chirality of molecular structures is paramount in many phenomena, including
enantioselective reactions, molecular self-assembly, biological processes and light or …
enantioselective reactions, molecular self-assembly, biological processes and light or …
Homo and hetero molecular 3D nanographenes employing a cyclooctatetraene scaffold
Two novel homo and hetero three-dimensional nanographenes, NG1 and NG2, featuring a
cyclooctatetraene core are designed, synthesized, and characterized. A concise and …
cyclooctatetraene core are designed, synthesized, and characterized. A concise and …
Surface-assisted dehydrogenative homocoupling of porphine molecules
The templated synthesis of porphyrin dimers, oligomers, and tapes has recently attracted
considerable interest. Here, we introduce a clean, temperature-induced covalent …
considerable interest. Here, we introduce a clean, temperature-induced covalent …
Comparing Ullmann coupling on noble metal surfaces: on‐surface polymerization of 1, 3, 6, 8‐tetrabromopyrene on Cu (111) and Au (111)
The on‐surface polymerization of 1, 3, 6, 8‐tetrabromopyrene (Br4Py) on Cu (111) and Au
(111) surfaces under ultrahigh vacuum conditions was investigated by a combination of …
(111) surfaces under ultrahigh vacuum conditions was investigated by a combination of …
Scanning probe microscopy in probing low-dimensional carbon-based nanostructures and nanomaterials
C Zhang, Z Yi, W Xu - Materials Futures, 2022 - iopscience.iop.org
Carbon, as an indispensable chemical element on Earth, has diverse covalent bonding
ability, which enables construction of extensive pivotal carbon-based structures in multiple …
ability, which enables construction of extensive pivotal carbon-based structures in multiple …