Resolution limit in infrared chemical imaging

Y Phal, L Pfister, PS Carney… - The Journal of Physical …, 2022 - ACS Publications
Chemical imaging combines the spatial specificity of optical microscopy with the spectral
selectivity of vibrational spectroscopy. Mid-infrared (IR) absorption imaging instruments are …

[HTML][HTML] Molecular dynamics simulation of linear polyethylene blends: Effect of molar mass bimodality on topological characteristics and mechanical behavior

A Moyassari, T Gkourmpis, MS Hedenqvist, UW Gedde - Polymer, 2019 - Elsevier
Blending different molar mass fractions of polyethylene (PE) in order to obtain materials with
higher fracture toughness has previously proven beneficial. Our approach has been to use …

Label-free infrared spectroscopic imaging reveals heterogeneity of β-sheet aggregates in Alzheimer's disease

MP Confer, BM Holcombe, AG Foes… - The journal of …, 2021 - ACS Publications
The aggregation of the amyloid beta (Aβ) protein into plaques is a pathological feature of
Alzheimer's disease (AD). While amyloid aggregates have been extensively studied in vitro …

3D orientation imaging of polymer chains with polarization-controlled coherent Raman microscopy

S Xu, Y **, YJ Lee - Journal of the American Chemical Society, 2022 - ACS Publications
Despite the ubiquity of three-dimensional (3D) anisotropic materials, their 3D molecular
alignment cannot be measured using conventional two-dimensional (2D) polarization …

Imaging 3D molecular orientation by orthogonal-pair polarization IR microscopy

S Xu, J Rowlette, YJ Lee - Optics Express, 2022 - opg.optica.org
Anisotropic molecular alignment occurs ubiquitously and often heterogeneously in three
dimensions (3D). However, conventional imaging approaches based on polarization can …

Measuring tie chains and trapped entanglements in semicrystalline polymers

AG McDermott, PJ DesLauriers, JS Fodor… - …, 2020 - ACS Publications
A label-free method for quantifying stress transmitter (or elastically effective molecule)
content (p) in semicrystalline polymers, including both tie molecules and bridging …

Minimum molecular weight and tie molecule content for ductility in polyethylenes of varying crystallinity

SH Cho, RA Register - Macromolecules, 2022 - ACS Publications
Semicrystalline polymers of low glass transition temperature, such as polyethylene (PE), can
be either brittle or ductile depending on their content of intercrystallite stress transmitters─ …

Intrahelical empty channels of nanoporous-crystalline α and β forms of PPO

M Golla, B Nagendra, C Daniel, P Rizzo… - European Polymer …, 2022 - Elsevier
A linear dichroism study of vibrational peaks of amorphous and semi-crystalline axially
stretched poly (2, 6-dimethyl-1, 4-phenylene) oxide (PPO) films shows an unusual behaviour …

Determining 3D molecular orientation from polarization-IR spectra: tutorial

YJ Lee - Journal of the Optical Society of America A, 2025 - opg.optica.org
Despite the ubiquity of molecular alignment in natural and synthesized materials, accurate
map** of three-dimensional (3D) molecular orientations with sufficient spatial resolving …

Three-Dimensional Molecular Orientation Imaging of a Semicrystalline Polymer Film under Shear Deformation

S Xu, CR Snyder, J Rowlette, YJ Lee - Macromolecules, 2022 - ACS Publications
The 3D molecular orientations of polymer chains are imaged and compared for a quiescent
spherulite region and a shear-deformed region of a semicrystalline poly (ε-caprolactone) …