Chemical reaction networks form the heart of microkinetic models, which are one of the key
tools available for gaining detailed mechanistic insight into heterogeneous catalytic …

The electrocatalytic oxygen evolution reaction (OER) supplies the protons and electrons
needed to transform renewable electricity into chemicals and fuels. However, the OER is …

Electro-, photo-, and photoelectrocatalysis play a critical role toward the realization of a
sustainable energy economy. They facilitate numerous redox reactions in energy storage …

The design of heterogeneous catalysts relies on understanding the fundamental surface
kinetics that controls catalyst performance, and microkinetic modeling is a tool that can help …

Despite the dedicated search for novel catalysts for fuel cell applications, the intrinsic
oxygen reduction reaction (ORR) activity of materials has not improved significantly over the …

This Perspective argues that most redox reactions of materials at an interface with a protic
solution involve net proton-coupled electron transfer (PCET)(or other cation-coupled ET) …

It has been over twenty years since the linear scaling of reaction intermediate adsorption
energies started to coin the fields of heterogeneous and electrocatalysis as a blessing and a …

The active sites of heterogeneous catalysts can be difficult to identify and understand, and,
hence, the introduction of active sites into catalysts to tailor their function is challenging …

A fundamental question in the electrochemical CO2 reduction reaction (CO2RR) is how to
rationally control the catalytic selectivity. For instance, adding a CO-selective cocatalyst like …

In this Review, we discuss the state-of-the-art understanding of non-precious transition metal
oxides that catalyze the oxygen reduction and evolution reactions. Understanding and …