B–H Functionalization of Hydrogen-Rich [(Cp*V)2(B2H6)2]: Synthesis and Structures of [(Cp*V)2(B2X2)2H8] (X = Cl, SePh; Cp* = η5-C5Me5)
A Haridas, S Kar, B Raghavendra, T Roisnel… - …, 2019 - ACS Publications
We have recently reported the perchlorinated diniobaborane species [(Cp* Nb) 2 (B2H4Cl2)
2] from [(Cp* Nb) 2 (B2H6) 2] using CCl4 as a chlorinating agent. In an attempt to isolate the …
2] from [(Cp* Nb) 2 (B2H6) 2] using CCl4 as a chlorinating agent. In an attempt to isolate the …
Metal-Rich Oxametallaboranes of Group 5 Metals: Synthesis and Structure of a Face-Fused μ7-Boride Cluster
R Prakash, A De, B Kirubakaran, S Ghosh - Inorganic Chemistry, 2018 - ACS Publications
Aerobic oxidation of metallaborane compounds is an unexplored field apart from the few
reports on accidental oxidation leading to oxametallaboranes. An effective method for the …
reports on accidental oxidation leading to oxametallaboranes. An effective method for the …
Chlorination of the terminal hydrogen atoms in the hydrogen-rich group 5 dimetallaboranes (Cp* M) 2 (B2H6) 2 (M= Nb, Ta)
R Prakash, K Bakthavachalam, B Varghese… - Journal of Organometallic …, 2017 - Elsevier
Abstract Reaction of Cp* NbCl 4 with 4 equivalents of LiBH 4. thf followed by thermolysis
with BH 3. thf in xylene yielded a chlorine substituted [(Cp* Nb) 2 (B 2 H 5 Cl) 2], 1 and its …
with BH 3. thf in xylene yielded a chlorine substituted [(Cp* Nb) 2 (B 2 H 5 Cl) 2], 1 and its …
Substitution at BH vertices of group 5 metallaborane clusters
A Haridas, S Bedajna, S Ghosh - Journal of Organometallic Chemistry, 2022 - Elsevier
Thermolysis of an in situ generated intermediate which was formed by the reaction of [Cp*
VCl 2] 3 (Cp*= η 5-C 5 Me 5) and LiBH 4. THF with excess of BH 3. THF (THF …
VCl 2] 3 (Cp*= η 5-C 5 Me 5) and LiBH 4. THF with excess of BH 3. THF (THF …
Structure and Electronic Properties of Metalloboranes with General Formula Cp*3(μ‐H)M3B8H8 (M=Cr, Mo and W): The Effect of the Size of the Metal
A family of Metalloborane of general formula Cp* 3 (μ‐H) M3B8H8 changing the metals M by
Cr, Mo, and W, were theoretically studied via Density Functional Theory (DFT) incorporating …
Cr, Mo, and W, were theoretically studied via Density Functional Theory (DFT) incorporating …
Cluster Compounds: Boranes, Heteroboranes, and Metallaboranes
The cluster compounds based on boranes, heteroboranes, and metallaboranes are widely
used in nanomedicine, targeted radiopharmaceuticals, medicinal imaging agents, cancer …
used in nanomedicine, targeted radiopharmaceuticals, medicinal imaging agents, cancer …
[CITATION][C] Polyhedral metallaboranes and metallacarboranes
S Kar, AN Pradhan, S Ghosh - 2022 - Elsevier
[CITATION][C] Cyclic and Non-Cyclic π-Complexes of Tantalum and Niobium
GE Forsythe, L Messerle - 2022 - Elsevier