Transfer hydrogenation (TH) with in situ generated hydrogen donor is of great importance in
reduction reactions, and an alternative strategy to traditional hydrogenation processes …

Selective hydrogenation of epoxides would be a direct and powerful approach for alcohol
synthesis, but it has proven to be elusive. Here, electrochemically epoxide hydrogenation …

A tunable photocatalytic method is reported for anti‐Markovnikov hydro‐and
aminooxygenation of unactivated alkenes using readily accessible ketoxime carbonates as …

The reduction of polar bonds, in particular carbonyl groups, is of fundamental importance in
organic chemistry and biology. Herein, we report a manganese pincer complex as a …

The reduction of epoxides is a powerful tool to access anti-Markovnikov alcohols, but
reported methods are poorly compatible with strongly electronically deactivated substrates …

Traditional catalyst development relies on multistep synthesis and isolation of ligand and
precatalyst. Designing a catalytic system that can be assembled in situ from easily …

We describe a unique catalytic system with an efficient coupling of Ti‐and Cr‐catalysis in a
reaction network that allows the use of [BH4]− as stoichiometric hydrogen atom and electron …

We describe a titanocene (III)‐catalyzed deuterosilylation of epoxides that provides β‐
deuterated anti‐Markovnikov alcohols with excellent D‐incorporation, in high yield, and …

Atom‐economical catalytic reactions are a highly enticing strategy because all atoms of the
starting materials are incorporated into the products. Catalytic hydrogenation of epoxides to …

Investigation of a variety of Lewis acids for the hydroboration-hydrolysis (reduction) of
ketones with amine-boranes has revealed that catalytic (10 mol%) titanium tetrachloride …