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Chirality in curved polyaromatic systems
Carbon allotropes constituted of sp2-hybridised carbon atoms display a variety of properties
that arise from their delocalised π-conjugated electronic structure. Apart from carbon's …
that arise from their delocalised π-conjugated electronic structure. Apart from carbon's …
Buckybowls: Corannulene and its derivatives
X Li, F Kang, M Inagaki - Small, 2016 - Wiley Online Library
Corannulene, a kind of bowl like polycyclic aromatic hydrocarbon (PAH), whose molecule is
composed of a central pentagon and five closely adjacent hexagons on the pentagon's five …
composed of a central pentagon and five closely adjacent hexagons on the pentagon's five …
Room‐Temperature Multiple Phosphorescence from Functionalized Corannulenes: Temperature Sensing and Afterglow Organic Light‐Emitting Diode
Corannulene‐derived materials have been extensively explored in energy storage and solar
cells, however, are rarely documented as emitters in light‐emitting sensors and organic light …
cells, however, are rarely documented as emitters in light‐emitting sensors and organic light …
Synthesis of inter-[60] fullerene conjugates with inherent chirality
Y Hashikawa, S Okamoto, Y Murata - Nature Communications, 2024 - nature.com
Coalescence of [60] fullerenes potentially produces hypothetical nanocarbon assemblies
with non-naturally occurring topologies. Since the discovery of [60] fullerene in 1985 …
with non-naturally occurring topologies. Since the discovery of [60] fullerene in 1985 …
[PDF][PDF] Electronic properties of trifluoromethylated corannulenes
All experiments were carried out under standard Schlenk conditions and argon atmosphere.
1, 2-Dichloroethane (DCE) and N, N-dimethylformamide were distilled from phosphorus …
1, 2-Dichloroethane (DCE) and N, N-dimethylformamide were distilled from phosphorus …
Linear [3]Spirobifluorenylene: An S-Shaped Molecular Geometry of p-Oligophenyls
J Oniki, T Moriuchi, K Kamochi, M Tobisu… - Journal of the …, 2019 - ACS Publications
An S-shaped p-oligophenyl derivative was synthesized, as exemplified by linear [3]
spirobifluorenylene (R, P, R/S, M, S)-1, which consisted of two p-sexiphenyls tied at the spiro …
spirobifluorenylene (R, P, R/S, M, S)-1, which consisted of two p-sexiphenyls tied at the spiro …
Structural, optical, and electrochemical properties of three-dimensional push–pull corannulenes
YL Wu, MC Stuparu, C Boudon… - The Journal of …, 2012 - ACS Publications
Electrochemically active corannulene derivatives with various numbers of electron-donating
4-(N, N-dimethylamino) phenylethynyl (1–4) or electron-withdrawing cyanobutadienyl …
4-(N, N-dimethylamino) phenylethynyl (1–4) or electron-withdrawing cyanobutadienyl …
Recent advances in stereodynamics and conformational analysis by dynamic NMR and theoretical calculations
D Casarini, L Lunazzi… - European Journal of …, 2010 - Wiley Online Library
Dynamic NMR spectroscopy can determine energy barriers due to internal motion over the
range of about 4.5–23 kcal mol–1. Conformational analysis of the frozen conformations can …
range of about 4.5–23 kcal mol–1. Conformational analysis of the frozen conformations can …
π− π interactions and solid state packing trends of polycyclic aromatic bowls in the indenocorannulene family: predicting potentially useful bulk properties
Solid state crystal structures are discussed and compared for all seven members of the
indenocorannulene family that have been recently synthesized by iterative microwave …
indenocorannulene family that have been recently synthesized by iterative microwave …
The INV24 test set: how well do quantum-chemical methods describe inversion and racemization barriers?
For years, there has been ongoing interest in experimentally and theoretically
understanding inversion and racemization processes. However, to the best of our …
understanding inversion and racemization processes. However, to the best of our …