Chirality in curved polyaromatic systems

M Rickhaus, M Mayor, M Juríček - Chemical Society Reviews, 2017 - pubs.rsc.org
Carbon allotropes constituted of sp2-hybridised carbon atoms display a variety of properties
that arise from their delocalised π-conjugated electronic structure. Apart from carbon's …

Buckybowls: Corannulene and its derivatives

X Li, F Kang, M Inagaki - Small, 2016 - Wiley Online Library
Corannulene, a kind of bowl like polycyclic aromatic hydrocarbon (PAH), whose molecule is
composed of a central pentagon and five closely adjacent hexagons on the pentagon's five …

Room‐Temperature Multiple Phosphorescence from Functionalized Corannulenes: Temperature Sensing and Afterglow Organic Light‐Emitting Diode

C Si, T Wang, AK Gupta, DB Cordes… - Angewandte …, 2023 - Wiley Online Library
Corannulene‐derived materials have been extensively explored in energy storage and solar
cells, however, are rarely documented as emitters in light‐emitting sensors and organic light …

Synthesis of inter-[60] fullerene conjugates with inherent chirality

Y Hashikawa, S Okamoto, Y Murata - Nature Communications, 2024 - nature.com
Coalescence of [60] fullerenes potentially produces hypothetical nanocarbon assemblies
with non-naturally occurring topologies. Since the discovery of [60] fullerene in 1985 …

[PDF][PDF] Electronic properties of trifluoromethylated corannulenes

BM Schmidt, S Seki, B Topolinski… - Angewandte Chemie …, 2012 - researchgate.net
All experiments were carried out under standard Schlenk conditions and argon atmosphere.
1, 2-Dichloroethane (DCE) and N, N-dimethylformamide were distilled from phosphorus …

Linear [3]Spirobifluorenylene: An S-Shaped Molecular Geometry of p-Oligophenyls

J Oniki, T Moriuchi, K Kamochi, M Tobisu… - Journal of the …, 2019 - ACS Publications
An S-shaped p-oligophenyl derivative was synthesized, as exemplified by linear [3]
spirobifluorenylene (R, P, R/S, M, S)-1, which consisted of two p-sexiphenyls tied at the spiro …

Structural, optical, and electrochemical properties of three-dimensional push–pull corannulenes

YL Wu, MC Stuparu, C Boudon… - The Journal of …, 2012 - ACS Publications
Electrochemically active corannulene derivatives with various numbers of electron-donating
4-(N, N-dimethylamino) phenylethynyl (1–4) or electron-withdrawing cyanobutadienyl …

Recent advances in stereodynamics and conformational analysis by dynamic NMR and theoretical calculations

D Casarini, L Lunazzi… - European Journal of …, 2010 - Wiley Online Library
Dynamic NMR spectroscopy can determine energy barriers due to internal motion over the
range of about 4.5–23 kcal mol–1. Conformational analysis of the frozen conformations can …

π− π interactions and solid state packing trends of polycyclic aromatic bowls in the indenocorannulene family: predicting potentially useful bulk properties

AS Filatov, LT Scott, MA Petrukhina - Crystal growth & design, 2010 - ACS Publications
Solid state crystal structures are discussed and compared for all seven members of the
indenocorannulene family that have been recently synthesized by iterative microwave …

The INV24 test set: how well do quantum-chemical methods describe inversion and racemization barriers?

L Goerigk, R Sharma - Canadian Journal of Chemistry, 2016 - cdnsciencepub.com
For years, there has been ongoing interest in experimentally and theoretically
understanding inversion and racemization processes. However, to the best of our …