Time‐resolved in situ monitoring of mechanochemical reactions
Mechanochemical transformations offer environmentally benign synthesis routes, whilst
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …
Toward Mechanistic Understanding of Mechanochemical Reactions Using Real-Time In Situ Monitoring
Conspectus The past two decades have witnessed a rapid emergence of interest in
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …
Raman spectroscopy for real-time and in situ monitoring of mechanochemical milling reactions
Solid-state milling has emerged as an alternative, sustainable approach for preparing
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …
Challenging the Ostwald rule of stages in mechanochemical cocrystallisation
Mechanochemistry provides an efficient, but still poorly understood route to synthesize and
screen for polymorphs of organic solids. We present a hitherto unexplored effect of the …
screen for polymorphs of organic solids. We present a hitherto unexplored effect of the …
Mechanochemical Preparation of Active Pharmaceutical Ingredients Monitored by In Situ Raman Spectroscopy
The mechanochemical preparation of silver sulfadiazine and dantrolene, two marketed
active pharmaceutical ingredients, was investigated by in situ Raman spectroscopy. For the …
active pharmaceutical ingredients, was investigated by in situ Raman spectroscopy. For the …
A review of recent developments for the in situ/operando characterization of nanoporous materials
This is a review on up-to-date in situ/operando methods for a comprehensive
characterization of nanoporous materials. The group of nanoporous materials is constantly …
characterization of nanoporous materials. The group of nanoporous materials is constantly …
Mechanochemical reaction kinetics scales linearly with impact energy
Inelastic collisions of the milling media in ball milling provide energy to the reaction mixture
required for chemical transformations. However, movement of the milling media also results …
required for chemical transformations. However, movement of the milling media also results …
Enantiotropic inconstancy, crystalline solid solutions and co-crystal in the salicylic acid–anthranilic acid system
The phase boundaries and thermodynamic properties of crystal phases in the salicylic acid
(SA)–anthranilic acid (AA) system have been determined experimentally. The complete …
(SA)–anthranilic acid (AA) system have been determined experimentally. The complete …
Isotope labeling reveals fast atomic and molecular exchange in mechanochemical milling reactions
Using tandem in situ monitoring and isotope-labeled solids, we reveal that
mechanochemical ball-milling overcomes inherently slow solid-state diffusion through …
mechanochemical ball-milling overcomes inherently slow solid-state diffusion through …
Screening nature of the van der Waals density functional method: A review and analysis of the many-body physics foundation
We review the screening nature and many-body physics foundation of the van der Waals
density functional (vdW-DF) method [Berland K et al 2015 Rep. Prog. Phys. 78 066501], a …
density functional (vdW-DF) method [Berland K et al 2015 Rep. Prog. Phys. 78 066501], a …