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Characterization of branched polysaccharides using multiple‐detection size separation techniques
The structure of branched polysaccharides involves a hierarchy of levels, from the
constituent sugars, then the branching pattern, up to the macromolecular architecture, and …
constituent sugars, then the branching pattern, up to the macromolecular architecture, and …
Perspectives on the viscoelasticity and flow behavior of entangled linear and branched polymers
We briefly review the recent advances in the rheology of entangled polymers and identify
emerging research trends and outstanding challenges, especially with respect to branched …
emerging research trends and outstanding challenges, especially with respect to branched …
Effects of grafting density on block polymer self-assembly: From linear to bottlebrush
Grafting density is an important structural parameter that exerts significant influences over
the physical properties of architecturally complex polymers. In this report, the physical …
the physical properties of architecturally complex polymers. In this report, the physical …
Synthesis and linear and nonlinear melt rheology of well-defined comb architectures of PS and PpMS with a low and controlled degree of long-chain branching
M Kempf, D Ahirwal, M Cziep, M Wilhelm - Macromolecules, 2013 - ACS Publications
Well-defined, monodisperse homopolymer comb architectures with varied number and
length of the branches under linear and nonlinear deformation were synthesized and …
length of the branches under linear and nonlinear deformation were synthesized and …
Detection and quantification of branching in polyacrylates by size-exclusion chromatography (SEC) and melt-state 13C NMR spectroscopy
P Castignolles, R Graf, M Parkinson, M Wilhelm… - Polymer, 2009 - Elsevier
Chain branching has been investigated in a homologous series of poly (n-alkyl
acrylates)(methyl, ethyl, n-butyl, n-hexyl) obtained by radical polymerization. The total …
acrylates)(methyl, ethyl, n-butyl, n-hexyl) obtained by radical polymerization. The total …
Reptate rheology software: Toolkit for the analysis of theories and experiments
We present a new, free, and open source reptate (rheology of entangled polymers: toolkit for
analysis of theory and experiment) software package for viewing, exchanging, and …
analysis of theory and experiment) software package for viewing, exchanging, and …
Uniaxial extensional rheology of well-characterized comb polymers
We present a detailed systematic investigation of the transient uniaxial extensional response
of a series of well-characterized, anionically synthesized comb polystyrenes and …
of a series of well-characterized, anionically synthesized comb polystyrenes and …
Start-up shear flow of a well-characterized entangled H-polymer
We present a systematic investigation of the linear viscoelasticity and nonlinear start-up
shear flow response of a well-characterized H-polystyrene, an archetype branched polymer …
shear flow response of a well-characterized H-polystyrene, an archetype branched polymer …
Macromolecular topology and rheology: beyond the tube model
D Vlassopoulos - Rheologica Acta, 2016 - Springer
The motion of entangled polymers is marked by their ability to make conformational
adjustments, which is mediated by their free ends. A credible account of the basic features of …
adjustments, which is mediated by their free ends. A credible account of the basic features of …
Combined synthesis, TGIC characterization, and rheological measurement and prediction of symmetric H polybutadienes and their blends with linear and star-shaped …
We report the synthesis and characterization by temperature gradient interaction
chromatography (TGIC) and rheometry of a symmetric H-shaped polybutadiene (PBd) that …
chromatography (TGIC) and rheometry of a symmetric H-shaped polybutadiene (PBd) that …