Cross‐Electrophile Coupling: Principles and New Reactions

MJ Goldfogel, L Huang, DJ Weix - Nickel Catalysis in Organic …, 2020 - Wiley Online Library
This chapter reviews the field of nickel‐catalyzed cross‐electrophile coupling, the cross‐
coupling of two different carbon electrophiles under reducing conditions. After briefly …

Nickel and palladium catalysis: Stronger demand than ever

VM Chernyshev, VP Ananikov - Acs Catalysis, 2022 - ACS Publications
Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

A Ni-MOF as fluorescent/electrochemical dual probe for ultrasensitive detection of picric acid from aqueous media

S Chongdar, U Mondal, T Chakraborty… - … Applied Materials & …, 2023 - ACS Publications
A water-stable, microporous, luminescent Ni (II)-based metal–organic framework (MOF)(Ni-
OBA-Bpy-18) with a 4-c uninodal sql topology was solvothermally synthesized using mixed …

Enantioselective C(sp3)–H Functionalization of Oxacycles via Photo-HAT/Nickel Dual Catalysis

S Xu, Y **, W Li, H Guo, Y Su, Z Li… - Journal of the …, 2023 - ACS Publications
The selective functionalization of ubiquitous but inert C–H bonds is highly appealing in
synthetic chemistry, but the direct transformation of hydrocarbons lacking directing groups …

Nickel Catalysis in Organic Synthesis

MJ Goldfogel, L Huang, DJ Weix - Nickel Catalysis in Organic Synthesis …, 2020 - elibrary.ru
This chapter reviews the field of nickel‐catalyzed cross‐electrophile coupling, the cross‐
coupling of two different carbon electrophiles under reducing conditions. After briefly …

Reductive alkyl–alkyl coupling from isolable nickel–alkyl complexes

S Al Zubaydi, S Waske, V Akyildiz, HF Starbuck… - Nature, 2024 - nature.com
The selective cross-coupling of two alkyl electrophiles to construct complex molecules
remains a challenge in organic synthesis,. Known reactions are optimized for specific …

Deciphering the mechanism of the Ni-photocatalyzed C‒O cross-coupling reaction using a tridentate pyridinophane ligand

H Na, LM Mirica - Nature communications, 2022 - nature.com
Photoredox nickel catalysis has emerged as a powerful strategy for cross-coupling
reactions. Although the involvement of paramagnetic Ni (I)/Ni (III) species as active …

Scrutinizing formally Ni IV centers through the lenses of core spectroscopy, molecular orbital theory, and valence bond theory

IM DiMucci, CJ Titus, D Nordlund, JR Bour… - Chemical …, 2023 - pubs.rsc.org
Nickel K-and L2, 3-edge X-ray absorption spectra (XAS) are discussed for 16 complexes
and complex ions with nickel centers spanning a range of formal oxidation states from II to …

Iridium-catalysed arylation of C–H bonds enabled by oxidatively induced reductive elimination

K Shin, Y Park, MH Baik, S Chang - Nature Chemistry, 2018 - nature.com
Direct arylation of C–H bonds is in principle a powerful way of preparing value-added
molecules that contain carbon–aryl fragments. Unfortunately, currently available synthetic …

Nickel‐Catalyzed Electrooxidative C− H Amination: Support for Nickel (IV)

SK Zhang, RC Samanta, N Sauermann… - … A European Journal, 2018 - Wiley Online Library
Nickel‐catalyzed electrochemical C− H aminations were accomplished by chemo‐and
position‐selective C− H activation with ample scope. Detailed mechanistic studies …