[HTML][HTML] Universal properties of relaxation and diffusion in complex materials: Originating from fundamental physics with rich applications

KL Ngai - Progress in Materials Science, 2023 - Elsevier
Complex materials are composed of basic units which invariably interact with anharmonic
potentials. It is well known that the dynamics of systems with anharmonic interaction are …

Impedance spectroscopy: Models, data fitting, and analysis

JR Macdonald - Solid state ionics, 2005 - Elsevier
First, several impedance spectroscopy models found useful for data fitting and interpretation
of dielectric-and conductive-system frequency data are briefly summarized and compared …

Frequency and temperature dependent dielectric and conductivity behavior of ceramics

B Sundarakannan, K Kakimoto, H Ohsato - Journal of applied physics, 2003 - pubs.aip.org
Dielectric and conductivity measurements were carried out on the potassium niobate
ceramics both as a function of temperature (50 to 550° C) and frequency (10 2 to 10 6 Hz). A …

Cage decay, near constant loss, and crossover to cooperative ion motion in ionic conductors: Insight from experimental data

KL Ngai, C León - Physical Review B, 2002 - APS
Experimental frequency-dependent conductivity relaxation spectra of a number of molten,
glassy, and crystalline ionic conductors that show both the presence of the near constant …

Coupling of caged molecule dynamics to JG β-relaxation: I

S Capaccioli, KL Ngai, MS Thayyil… - The Journal of Physical …, 2015 - ACS Publications
The paper (Sibik, J.; Elliott, SR; Zeitler, JAJ Phys. Chem. Lett. 2014, 5, 1968–1972) used
terahertz time-domain spectroscopy (THz-TDS) to study the dynamics of the polyalcohols …

Investigations of relaxation dynamics and observation of nearly constant loss phenomena in PEO20-LiCF3SO3-ZrO2 based polymer nano-composite electrolyte

T Dam, SN Tripathy, M Paluch, SS Jena, DK Pradhan - Electrochimica Acta, 2016 - Elsevier
The conduction mechanism of polymer nano-composite electrolytes are studied using
broadband dielectric spectroscopy over a wide range of frequency and temperature. The …

Observation of ionic transport and ion-coordinated segmental motions in composite (polymer-salt-clay) solid polymer electrolyte

T Dam, NK Karan, R Thomas, DK Pradhan, RS Katiyar - Ionics, 2015 - Springer
A solution casting method was successfully used to realize polymer nanocomposite
electrolytes consisting of polyethylene oxide as polymer host, lithium hexafluoroarsenate as …

Coupling of caged molecule dynamics to JG β-relaxation II: polymers

KL Ngai, S Capaccioli, D Prevosto… - The Journal of Physical …, 2015 - ACS Publications
At temperatures below the nominal glass transition temperature T gα, the structural α-
relaxation and the Johari–Goldstein (JG) β-relaxation are too slow to contribute to …

Tailoring disorder and dimensionality: strategies for improved solid oxide fuel cell electrolytes

J Garcia‐Barriocanal, A Rivera‐Calzada… - …, 2009 - Wiley Online Library
Towards cooler solid oxide fuel cells: Disorder and dimensionality (see picture) play an
important role in determining ion mobility of bulk and artificially nanolayered materials and …

Super-linear frequency dependence of ac conductivity of disordered Ag2S–Sb2S3 at cryogenic temperatures

JP Tiwari, K Shahi - Philosophical Magazine, 2007 - Taylor & Francis
The ac conductivity of a new class of disordered solids, ie mechanochemically synthesized
amorphous fast ion conducting Ag2S–Sb2S3 materials, has been investigated in the audio …