Lanthanide–radical single-molecule magnets: current status and future challenges

HD Li, SG Wu, ML Tong - Chemical Communications, 2023 - pubs.rsc.org
In the field of molecular magnetism, the lanthanide–radical (Ln–Rad) method has become
one of the most appealing tactics for introducing strong magnetic interactions and has …

Magnetic Bistability in an Organic Radical-Based Charge Transfer Cocrystal

W Lai, Y Bu, W **ao, H Liu, J Guo, L Zhao… - Journal of the …, 2023 - ACS Publications
We report herein an organic charge transfer cocrystal complex, consisting of a stable radical
TPVr and an electron acceptor TCNQF 4, as a rare sort of all-organic-based magnetic …

Reversible switchability of magnetic anisotropy and magnetodielectric effect induced by intermolecular motion

SN Du, D Su, ZY Ruan, YQ Zhou… - Angewandte Chemie …, 2022 - Wiley Online Library
Introducing magnetic switchability into artificial molecular machines is fascinating for precise
control of magnetism via external stimuli. Herein, a field‐induced CoII single‐molecule …

Photoelectromagnetic Responsive Adaptive Porous Frameworks through Dynamic Covalent Chemistry of Tetraarylethylene‐backboned Aryldicyanomethyl Radicals

X Wang, H Zhang, H Liu, G Xu, W Lai… - Angewandte Chemie …, 2023 - Wiley Online Library
Dynamic materials undergoing adaptive solid‐state transitions are attractive for soft
mechanics and information technology. Here, we report a novel porous framework system …

Wolmershäuser radicals: Chemistry and materials science

AA Buravlev, AY Makarov, OA Rakitin… - Mendeleev …, 2023 - Elsevier
Chemistry and materials science of stable 1, 3, 2-benzodi-thiazolyls (Wolmershäuser
radicals) are discussed. These easily-accessible chromogenic and redox-active compounds …

Charge transport of F4TCNQ with different electronic states in single-molecule junctions

A Tang, Y Li, R Wang, J Yang, C Ma, Z Li… - Chemical …, 2023 - pubs.rsc.org
The molecular conductance of 2, 3, 5, 6-tetrafluoro-7, 7, 8, 8,-tetracyano-quinodimethane
(F4TCNQ) with different electronic states (neutral, radical anion, and dianion) was …

Homoconjugation Mediated Spin-Spin Coupling in Triptycene Nitronyl Nitroxide Diradicals

C Shi, L Gao, M Baumgarten, D Wei, Z Xu, W Wang… - Magnetochemistry, 2023 - mdpi.com
In contrast to diradical linked by π-conjugation, there have been only a limited number of
studies reported for those linked by homoconjugation systems. Bis (nitronyl nitroxide) …

Crystallization‐Induced Dimerization and Solution‐Phase Bond Dissociation of Stable Dibenzoolympicenyl Radicals

X Zhang, H He, C Ge, Q **ang, S Sato… - Angewandte Chemie …, 2025 - Wiley Online Library
Crystallization of organic materials can lead to different assembly structure with different
reactivity, but this phenomenon is rarely observed for delocalized hydrocarbon radicals. This …

Magnetic bistable organic ionic plastic crystal with room temperature ion conductivity comparable to NASICON and superionic conduction in a broad temperature …

Y Qian, J Zhang, YM Wang, WW Yao… - Materials Chemistry …, 2022 - pubs.rsc.org
Organic ion plastic crystals (OIPCs) show promising applications in various all solid-state
electrochemical energy storage devices. In this regard, superionic conducting OIPCs with a …

Long carbon–carbon bonds and beyond

M Kishimoto, T Kubo - Chemical Physics Reviews, 2024 - pubs.aip.org
Advances in synthetic organic chemistry have facilitated the preparation and exploration of
compounds exhibiting unusual bonding states. This review delves into carbon–carbon …