The activation of dinitrogen by coordination to transition metal ions is a widely used and
promising approach to the utilization of Earth's most abundant nitrogen source for chemical …

The formation of multicarbon products from CO2 electroreduction is challenging on materials
other than Cu-based catalysts. Ag has been known to be a typical metal catalyst, producing …

A complete cleavage of the triple bond of N2 by fluoroborylene (: BF) was achieved in a low‐
temperature N2 matrix by the formation of the four‐membered heterocycle FB (μ‐N) 2BF …

Reduction and fixation of CO 2 in natural systems via solar energy generate diverse
products, ranging from small molecules to biomolecules. To date, only a few multicarbon …

We report the room temperature dimerization of carbon monoxide mediated by C4/C5‐
vicinal anionic dicarbenes Li (ADC)(ADC= ArC {(Dipp) NC} 2; Dipp= 2, 6‐iPr2C6H3; Ar= Ph …

High pressure technique can greatly enrich the chemistry research by innovating the
traditional research paradigm. Recently, tremendous attentions have been paid to the high …

Wir berichten über die Dimerisierung von Kohlenmonoxid bei Raumtemperatur mittels
anionischer C4/C5‐Dicarbene Li (ADC)(ADC= ArC {(Dipp) NC} 2; Dipp= 2, 6‐iPr2C6H3; Ar …

The carbon dioxide reduction reaction (CO2RR) is one of the most promising solutions for
realizing carbon neutralization via converting the emitted CO2 into value‐added chemicals …

Current studies have highlighted the crucial role of spin in electrocatalytic reactions. Spin
regulation can effectively reduce the energy cost of spin flip** and accelerate reactions. A …

We present the results of DFT calculations and a thorough bonding analysis of the neutral
and charged complexes of the elusive C2O2 species stabilized by two NHC ligands. It is …