Metal–organic network-forming glasses

N Ma, S Horike - Chemical Reviews, 2022 - ACS Publications
The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …

Understanding and controlling the nucleation and growth of metal–organic frameworks

BP Carpenter, AR Talosig, B Rose… - Chemical Society …, 2023 - pubs.rsc.org
Metal–organic frameworks offer a diverse landscape of building blocks to design high
performance materials for implications in almost every major industry. With this diversity …

Novel rod-like [Cu (phen) 2 (OAc)]· PF6 complex for high-performance visible-light-driven photocatalytic degradation of hazardous organic dyes: DFT approach …

S Zinatloo-Ajabshir, S Rakhshani, Z Mehrabadi… - Journal of …, 2024 - Elsevier
A novel octahedral distorted coordination complex was formed from a copper transition
metal with a bidentate ligand (1, 10-Phenanthroline) and characterized by Ultraviolet–visible …

Immobilization of lewis basic sites into a stable ethane-selective MOF enabling one-step separation of ethylene from a ternary mixture

XW Gu, JX Wang, E Wu, H Wu, W Zhou… - Journal of the …, 2022 - ACS Publications
Purification of C2H4 from a ternary C2H2/C2H6/C2H4 mixture by one-step adsorption
separation is of prime importance but challenging in the petrochemical industry; however …

Optimizing Fe‐3d Electron Delocalization by Asymmetric Fe–Cu Diatomic Configurations for Efficient Anion Exchange Membrane Fuel Cells

Y Liu, S Yuan, C Sun, C Wang, X Liu… - Advanced Energy …, 2023 - Wiley Online Library
Precisely designing asymmetric diatomic configurations and studying their electronic
regulation effect for improving the oxygen reduction reaction (ORR) performance are …

Microplastics and nanoplastics analysis: options, imaging, advancements and challenges

C Fang, Y Luo, R Naidu - TrAC Trends in Analytical Chemistry, 2023 - Elsevier
As emerging contaminants, microplastics and nanoplastics pose analytical challenges to the
scientific community due to the small size, diverse composition and complex environmental …

Active mechanisorption driven by pum** cassettes

L Feng, Y Qiu, QH Guo, Z Chen, JSW Seale, K He… - Science, 2021 - science.org
Over the past century, adsorption has been investigated extensively in equilibrium systems,
with a focus on the van der Waals interactions associated with physisorption and electronic …

Tailoring Coordination Microenvironment of Cu(I) in Metal–Organic Frameworks for Enhancing Electroreduction of CO2 to CH4

Y Zhang, Q Zhou, ZF Qiu, XY Zhang… - Advanced Functional …, 2022 - Wiley Online Library
The coordination microenvironment of metal active sites in metal–organic frameworks
(MOFs) plays a crucial role in its performance for electrochemical CO2 reduction reaction …

Metal–organic frameworks as catalytic selectivity regulators for organic transformations

J Guo, Y Qin, Y Zhu, X Zhang, C Long… - Chemical Society …, 2021 - pubs.rsc.org
Selective organic transformations using metal–organic frameworks (MOFs) and MOF-based
heterogeneous catalysts have been an intriguing but challenging research topic in both the …

Construction of Negative Electrostatic Pore Environments in a Scalable, Stable and Low‐Cost Metal‐organic Framework for One‐Step Ethylene Purification from …

HM Wen, C Yu, M Liu, C Lin, B Zhao, H Wu… - Angewandte …, 2023 - Wiley Online Library
One‐step separation of C2H4 from ternary C2 mixtures by physisorbents remains a
challenge to combine excellent separation performance with high stability, low cost, and …