Assembling inorganic nanocrystal gels

AM Green, CK Ofosu, J Kang, EV Anslyn… - Nano Letters, 2022 - ACS Publications
Inorganic nanocrystal gels retain distinct properties of individual nanocrystals while offering
tunable, network-structure-dependent characteristics. We review different mechanisms for …

Colloidal nanocrystal gels from thermodynamic principles

ZM Sherman, AM Green, MP Howard… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Gels assembled from solvent-dispersed nanocrystals are of interest for
functional materials because they promise the opportunity to retain distinctive properties of …

Megamolecule Self-Assembly Networks: A Combined Computational and Experimental Design Strategy

J Wu, Z Gu, JA Modica, S Chen… - Journal of the …, 2024 - ACS Publications
This work describes the use of computational strategies to design megamolecule building
blocks for the self-assembly of lattice networks. The megamolecules are prepared by …

[HTML][HTML] Modular mixing in plasmonic metal oxide nanocrystal gels with thermoreversible links

J Kang, ZM Sherman, HSN Crory, DL Conrad… - The Journal of …, 2023 - pubs.aip.org
Gelation offers a powerful strategy to assemble plasmonic nanocrystal networks
incorporating both the distinctive optical properties of constituent building blocks and …

Impact of Linker Length on Biomolecular Condensate Formation

T GrandPre, Y Zhang, AGT Pyo, B Weiner, JL Li… - PRX Life, 2023 - APS
Biomolecular condensates are membraneless organelles formed via phase separation of
macromolecules, typically consisting of bond-forming “stickers” connected by flexible …

[HTML][HTML] Effects of linker flexibility on phase behavior and structure of linked colloidal gels

MP Howard, ZM Sherman, AN Sreenivasan… - The Journal of …, 2021 - pubs.aip.org
Colloidal nanocrystal gels can be assembled using a difunctional “linker” molecule to
mediate bonding between nanocrystals. The conditions for gelation and the structure of the …

[HTML][HTML] Dynamics of equilibrium-linked colloidal networks

T Kwon, TA Wilcoxson, DJ Milliron… - The Journal of Chemical …, 2022 - pubs.aip.org
Colloids that attractively bond to only a few neighbors (eg, patchy particles) can form
equilibrium gels with distinctive dynamic properties that are stable in time. Here, we use a …

Phase equilibrium studies in the geothermal energy development: The effect of hydrogen bond on the multi-component fluid

T Zhang, L Gong, S Sun, CY Zhu - ACS omega, 2023 - ACS Publications
Geothermal energy has become an emerging resource with both large reserves and
environmental friendliness and is playing an increasingly important role in the current …

Colorimetric quantification of linking in thermoreversible nanocrystal gel assemblies

J Kang, SA Valenzuela, EY Lin, MN Dominguez… - Science …, 2022 - science.org
Nanocrystal gels can be responsive, tunable materials, but designing their structure and
properties is challenging. By using reversibly bonded molecular linkers, gelation can be …

A simple second order thermodynamic perturbation theory for associating fluids

BD Marshall - arxiv preprint arxiv:2110.04575, 2021 - arxiv.org
An approximation within Wertheim's second order perturbation theory is proposed which
allows for the development of a general solution for pure component fluids with an arbitrary …