Water as an active constituent in cell biology

P Ball - Chemical reviews, 2008 - ACS Publications
When Szent-Györgyi called water the “matrix of life”, 1 he was echoing an old sentiment.
Paracelsus in the 16th century said that “water was the matrix of the world and of all its …

Cosolvent effects on protein stability

DR Canchi, AE García - Annual review of physical chemistry, 2013 - annualreviews.org
Proteins are marginally stable, and the folding/unfolding equilibrium of proteins in aqueous
solution can easily be altered by the addition of small organic molecules known as …

Hydrogels in emerging technologies for type 1 diabetes

S Fuchs, AU Ernst, LH Wang, K Shariati… - Chemical …, 2020 - ACS Publications
Type 1 diabetes therapies that afford tighter glycemic control in a more manageable and
painless manner for patients has remained a central focus of next-generation diabetes …

Urea as a hydrogen bond producer for fabricating mechanically very strong hydrogels

Y Wu, Y Shi, H Wang - Macromolecules, 2023 - ACS Publications
Hydrogen bonding plays a very important role in the construction and stabilization of natural
and synthetic polymeric materials. Urea is generally considered and used as a hydrogen …

Urea denaturation by stronger dispersion interactions with proteins than water implies a 2-stage unfolding

L Hua, R Zhou, D Thirumalai… - Proceedings of the …, 2008 - National Acad Sciences
The mechanism of denaturation of proteins by urea is explored by using all-atom
microseconds molecular dynamics simulations of hen lysozyme generated on BlueGene/L …

Mechanism by which 2, 2, 2-trifluoroethanol/water mixtures stabilize secondary-structure formation in peptides: a molecular dynamics study

D Roccatano, G Colombo… - Proceedings of the …, 2002 - National Acad Sciences
Molecular dynamics simulation techniques have been used to investigate the effect of 2, 2, 2-
trifluoroethanol (TFE) as a cosolvent on the stability of three different secondary structure …

Microneedle-array patches loaded with dual mineralized protein/peptide particles for type 2 diabetes therapy

W Chen, R Tian, C Xu, BC Yung, G Wang, Y Liu… - Nature …, 2017 - nature.com
The delivery of therapeutic peptides for diabetes therapy is compromised by short half-lives
of drugs with the consequent need for multiple daily injections that reduce patient …

Dewetting and hydrophobic interaction in physical and biological systems

BJ Berne, JD Weeks, R Zhou - Annual review of physical …, 2009 - annualreviews.org
Hydrophobicity manifests itself differently on large and small length scales. This review
focuses on large-length-scale hydrophobicity, particularly on dewetting at single …

Interactions between hydrophobic and ionic solutes in aqueous guanidinium chloride and urea solutions: lessons for protein denaturation mechanism

EP O'Brien, RI Dima, B Brooks… - Journal of the American …, 2007 - ACS Publications
In order to clarify the mechanism of denaturant-induced unfolding of proteins we have
calculated the interactions between hydrophobic and ionic species in aqueous guanidinium …

Urea's action on hydrophobic interactions

R Zangi, R Zhou, BJ Berne - Journal of the American Chemical …, 2009 - ACS Publications
For more than a century, urea has been commonly used as an agent for denaturing proteins.
However, the mechanism behind its denaturing power is still not well understood. Here we …