The main advances in the chemistry of acetylene in superbasic media achieved over the last
five years are analyzed. Particular emphasis is placed on the ethynylation of aldehydes and …

The currently known methods for the preparation of vinyl ethers, vinyl sulfides and enamines
are analyzed and described systematically. The published data on the reactions of alcohols …

Gold(III)-Catalyzed Double Hydroamination of o-Alkynylaniline with Terminal Alkynes Leading
to N-Vinylindoles | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In …

Vinylation of various azoles (pyrrole, indole, carbazole, and their derivatives) and
phenothiazine with vinyl bromides catalyzed by palladium− phosphine complexes results in …

An efficient and straightforward copper‐catalyzed method allowing vinylation of N‐or O‐
nucleophiles with di‐or trisubstituted vinyl bromides is reported. The procedure is applicable …

A novel methodology for the preparation of trideuterovinyl derivatives of high purity directly
from alcohols, thiols, and NH-compounds was developed. Commercially available calcium …

Herein, we describe a convenient protocol for the synthesis of N-alkenylated heterocycles
using abundant ketone electrophiles and T3P as a water scavenger under microwave …

A general and efficient palladium-catalyzed oxidative cross-coupling reaction of N-
tosylhydrazones with indoles providing N-vinylindoles has been developed. The reaction …

A copper-catalyzed methodology for the coupling of vinyl bromides with azoles has been
developed. This protocol uses a combination of 10 mol% of copper iodide and 20 mol% of …

The polymerization of three N-vinylindole derivatives, N-vinylindole (NVIn), 2-methyl-N-
vinylindole (2MNVIn), and 3-methyl-N-vinylindole (3MNVIn), were carried out by reversible …