Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Electrochemistry utilizes electrons as a potent, controllable, and traceless alternative to
chemical oxidants or reductants, and typically offers a more sustainable option for achieving …

Conspectus Carbon dioxide (CO2) is recognized as a greenhouse gas and a common
waste product. Simultaneously, it serves as an advantageous and commercially available …

Carbon dioxide radical anion (CO2•–) is a highly reactive nucleophilic radical species that
has recently emerged in organic chemistry as a strong single electron donor (reductant) and …

Carboxylation of easily available alkenes with CO2 is highly important to afford value‐added
carboxylic acids. Although dicarboxylation of activated alkenes, especially 1, 3‐dienes, has …

The chemical conversion of carbon dioxide (CO2) into high-value chemicals or fuels is
exceedingly attractive due to its green and sustainable features. However, practical …

Herein, we report an electroreduction of unactivated alkyl alkenes enabled by [Fe]-H, which
is provided through the combination of anodic iron salts and the silane generated in situ via …

Organic electrosynthesis is a green strategy for the synthesis of valuable molecules.
Electrochemical reactions using sacrificial metal anodes enable new reactivity to be …

Herein, a direct, metal‐free, and site‐selective electrochemical C− H carboxylation of arenes
by reductive activation using CO2 as the economic and abundant carboxylic source was …

Herein, an electroreductive carboxylation of organic carbon‐halogen bonds (X= Br and Cl)
promoted by catalytic amounts of naphthalene as an organic mediator is reported. This …