Selective alkane transformations via radicals and radical cations: Insights into the activation step from experiment and theory

AA Fokin, PR Schreiner - Chemical reviews, 2002 - ACS Publications
As the main constituent of natural gas, alkanes are arguably Nature's most plentiful organic
base chemicals that are easily accessible. Chemists have long coveted the use of alkanes …

Understanding reactivity patterns of radical cations

M Schmittel, A Burghart - Angewandte Chemie International …, 1997 - Wiley Online Library
Over the last 15 years electron transfer activation has emerged as a valuable concept for
accomplishing novel reactions and has found widespread application in the selective …

[KSIĄŻKA][B] CRC Handbook of Organic Photochemistry and Photobiology, Volumes 1 & 2

WM Horspool, F Lenci - 2003 - taylorfrancis.com
The second edition of this best-selling handbook is bigger, more comprehensive, and now
completely current. In addition to thorough updates to the discussions featured in the first …

[HTML][HTML] Norbornadiene–quadricyclane—an effective molecular system for the storage of solar energy

B VA, AD Dubonosov, VI Minkin… - Russ. Chem …, 1991 - russchemrev.org
The results of studies on intramolecular interconversions in systems of norbornadiene⇄
quadricyclane and their derivatives are classified and discussed. The mechanisms of the …

Norbornadiene–quadricyclane as an abiotic system for the storage of solar energy

AD Dubonosov, VA Bren… - Russian chemical …, 2002 - pubs.rsc.org
Data on the valence isomerisation of norbornadiene and its derivatives into the
corresponding quadricyclanes published between 1990 and 2001 are considered and …

Organic radical ions in rigid systems

T Shida, E Haselbach, T Bally - Accounts of Chemical Research, 1984 - ACS Publications
Radical ions are important chemical entities occurring in one-electron oxidation or reduction
of closed-shell molecules. They are produced in chemical reactions as well as upon …

Kinetics and mechanisms of reactions of organic cation radicals in solution

O Hammerich, VD Parker - Advances in physical organic chemistry, 1984 - Elsevier
Publisher Summary The dimerization of cation radicals of simple benzene derivatives is
usually accompanied by the formation of the corresponding biphenyl derivative. This, by …

Driving the quadricyclane-to-norbornadiene isomerization by charge separation with perylenediimide as electron acceptor

W Zika, A Leng, R Weiß, S Pintér, CM Schüßlbauer… - Chemical …, 2023 - pubs.rsc.org
Through comprehensive photo-assays, this study investigates the reaction coordinate
governing the interconversion between quadricyclane (QC) and norbornadiene (NBD) upon …

Organic radical cations in fluid solution: unusual structures and rearrangements

HD Roth - Accounts of Chemical Research, 1987 - ACS Publications
Organic radical ions are important intermediates in a wide variety of chemical processes,
and they also command attention because of a multitude of unusual structure types and a …

Nuclear spin polarization effects in radical ion pair reactions. Comparison between triplet state and radical ion reactivity

HD Roth, MLM Schilling - Journal of the American Chemical …, 1981 - ACS Publications
Abstract; A series of radical cations has been generated from appropriate hydrocarbonsby
photoinitiated electron transfer to chloranil and cyanosubstituted aromatic hydrocarbons …