Recently, late-transition-metal-catalyzed chain-walking polymerization has emerged as a
promising method for synthesizing a range of polyethylenes, including linear, branched, and …

We review the results of Monte Carlo studies of chosen nonlinear optical effects in host-
guest systems, using methods based on the bond-fluctuation model (BFM) for a polymer …

The advancement of high-temperature interaction chromatography (HT-IC) is a key
milestone in polyolefin characterization. Temperature gradient interaction chromatography …

Polyolefins with branches produced by ethylene alone via chain walking are highly desired
in industry. Selective branch formation from uncontrolled chain walking is a long-standing …

The branching type and amount in polyolefins have a significant impact on the material
properties. In this study, a family of “sandwich” or “semi-sandwich” α-diimine ligands with …

Radical ring-opening polymerization (RROP) of 2-methylene-1, 3-dioxepane (MDO) leads to
a polymer that is structurally similar to poly (ε-caprolactone)(PCL). Despite the similarities …

The synthesis of single chain nanoparticles (SCNPs) is a vibrant field in macromolecular
science, enabled by a rich variety of synthetic strategies to induce macromolecular chain …

Polyolefin engineering and design are at the forefront of a significant number of research
and development laboratories, hel** to bring about new and highly specific materials for …

We present a new strategy to regulate branching in chain‐walking olefin polymerization by
triggering a rapid isomerization of 1‐alkene monomers into internal olefins by adding a …

Chain-walking (CW) catalysis applied to α-olefin polymerization gives rise to structurally
unparalleled macromolecules with diverse topological and rheological properties. The …