Strategies to address key challenges of metallacycle/metallacage-based supramolecular coordination complexes in biomedical applications

D Xu, Y Li, S Yin, F Huang - Chemical Society Reviews, 2024 - pubs.rsc.org
Owing to their capacity for dynamically linking two or more functional molecules,
supramolecular coordination complexes (SCCs), exemplified by two-dimensional (2D) …

Recent developments in the construction and applications of platinum-based metallacycles and metallacages via coordination

Y Sun, C Chen, J Liu, PJ Stang - Chemical Society Reviews, 2020 - pubs.rsc.org
Coordination-driven suprastructures have attracted much interest due to their unique
properties. Among these structures, platinum-based architectures have been broadly …

Pt (II)/Pd (II)‐Based Metallosupramolecular Architectures as Light Harvesting Systems and their Applications

D Bokotial, K Acharyya, A Chowdhury… - Angewandte Chemie …, 2024 - Wiley Online Library
The development of artificial light‐harvesting systems mimicking the natural photosynthesis
method is an ever‐growing field of research. Numerous systems such as polymers, metal …

Macrocycles and cages based on tetraphenylethylene with aggregation-induced emission effect

HT Feng, YX Yuan, JB **ong, YS Zheng… - Chemical Society …, 2018 - pubs.rsc.org
Organic molecules with an aggregation-induced emission (AIE) effect have recently been
attracting more and more attention due to their colossal potential in solid emitters and …

[2, 2] Paracyclophanes-based double helicates for constructing artificial light-harvesting systems and white LED device

Z Lian, J He, L Liu, Y Fan, X Chen, H Jiang - Nature Communications, 2023 - nature.com
The construction of efficient artificial light-harvesting systems (ALHSs) is of vital importance
in utilizing solar energy. Herein, we report the non-covalent syntheses of double helicates …

An NIR Discrete Metallacycle constructed from Perylene Bisimide and Tetraphenylethylene Fluorophores for imaging‐guided cancer Radio‐chemotherapy

Y Ding, Z Tong, L **, B Ye, J Zhou, Z Sun… - Advanced …, 2022 - Wiley Online Library
To promote the clinical theranostic performances of platinum‐based anticancer drugs,
imaging capability is urgently desired, and their chemotherapeutic efficacy needs to be …

Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

Photophysical properties of organoplatinum (II) compounds and derived self-assembled metallacycles and metallacages: fluorescence and its applications

ML Saha, X Yan, PJ Stang - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Over the past couple of decades, coordination-driven self-assembly has
evolved as a broad multidisciplinary domain that not only covers the syntheses of …

Multicomponent platinum (II) cages with tunable emission and amino acid sensing

M Zhang, ML Saha, M Wang, Z Zhou… - Journal of the …, 2017 - ACS Publications
The syntheses, characterization, and emission properties of three tetragonal prismatic
cages, 4a–4c, constructed from eight 90° Pt (II) acceptors, four linear dipyridyl ligands, and …

Fluorescent metallacage-core supramolecular polymer gel formed by orthogonal metal coordination and host–guest interactions

C Lu, M Zhang, D Tang, X Yan, ZY Zhang… - Journal of the …, 2018 - ACS Publications
Herein, we report the preparation of a multifunctional metallacage-core supramolecular gel
by orthogonal metal coordination and host–guest interactions. A tetragonal prismatic cage …