Bistable spin‐crossover nanoparticles for molecular electronics

R Torres‐Cavanillas, M Gavara‐Edo… - Advanced …, 2024 - Wiley Online Library
The field of spin‐crossover complexes is rapidly evolving from the study of the spin transition
phenomenon to its exploitation in molecular electronics. Such spin transition is gradual in a …

Emerging trends in spin crossover (SCO) based functional materials and devices

KS Kumar, M Ruben - Coordination Chemistry Reviews, 2017 - Elsevier
The design and synthesis of functional molecules with controllable properties are at the
forefront of modern materials chemistry research due to their diverse applicability, especially …

[HTML][HTML] Structural analysis of spin-crossover materials: From molecules to materials

E Collet, P Guionneau - Comptes Rendus Chimie, 2018 - Elsevier
In molecular spin-crossover materials, the spin-state switching is strongly coupled with
changes in the structural degrees of freedom, which play a central role in the alteration of …

[HTML][HTML] Spin-crossover nanoparticles and nanocomposite materials

L Salmon, L Catala - Comptes Rendus Chimie, 2018 - Elsevier
This contribution reports on the state of the art of the elaboration and the application of
nanoparticles (NPs) and nanohybrid/nanocomposite materials based on spin-crossover …

Colossal expansion and fast motion in spin-crossover@ polymer actuators

M Piedrahita-Bello, JE Angulo-Cervera… - Materials …, 2021 - pubs.rsc.org
Bilayer spin crossover (SCO)@ polymer nanocomposites show robust and controllable
actuation cycles upon an electrical stimulus. The anisotropic shape of the embedded …

Design of bistable gold@ spin‐crossover core–shell nanoparticles showing large electrical responses for the spin switching

R Torres‐Cavanillas, R Sanchis‐Gual… - Advanced …, 2019 - Wiley Online Library
A simple chemical protocol to prepare core–shell gold@ spin‐crossover (Au@ SCO)
nanoparticles (NPs) based on the 1D spin‐crossover [Fe (Htrz) 2 (trz)](BF4) coordination …

Room temperature optoelectronic devices operating with spin crossover nanoparticles

JF Dayen, N Konstantinov, M Palluel, N Daro… - Materials …, 2021 - pubs.rsc.org
Molecular systems can exhibit multi-stimuli switching of their properties, with spin crossover
materials having unique magnetic transition triggered by temperature and light, among …

Photo‐thermal switching of individual plasmonically activated spin crossover nanoparticle imaged by ultrafast transmission electron microscopy

Y Hu, M Picher, NM Tran, M Palluel… - Advanced …, 2021 - Wiley Online Library
Spin crossover (SCO) is a promising switching phenomenon when implemented in
electronic devices as molecules, thin films or nanoparticles. Among the properties …

Spin crossover {[Fe (atrz) 3](OTs) 2} n monolith: a green synthesis approach for Robust switchable materials

A Martinez-Martinez, P Albacete… - Dalton …, 2024 - pubs.rsc.org
This work presents a straightforward, room-temperature synthesis of a robust {[Fe (atrz)
3](OTs) 2} n monolith. This approach offers a green alternative to traditional nanoparticle …

Lattice defects in sub-micrometer spin-crossover crystals studied by electron diffraction

H Mba, M Picher, N Daro, M Marchivie… - The Journal of …, 2023 - ACS Publications
Spin-crossover particles of [Fe (Htrz) 2trz](BF4) with sizes of some hundred nanometers are
studied by in situ electron microscopy. Despite their high radiation sensitivity, it was possible …