Recent progress in actinide borate chemistry
The use of molten boric acid as a reactive flux for synthesizing actinide borates has been
developed in the past two years providing access to a remarkable array of exotic materials …
developed in the past two years providing access to a remarkable array of exotic materials …
Evaluation of f-element borate chemistry
MA Silver, TE Albrecht-Schmitt - Coordination Chemistry Reviews, 2016 - Elsevier
The synthesis, structure elucidation, and spectroscopic measurements of a myriad of new, f-
element borates has revealed the unusual effects that this electron-rich oxoanion has on the …
element borates has revealed the unusual effects that this electron-rich oxoanion has on the …
A revised and expanded structure hierarchy of natural and synthetic hexavalent uranium compounds
AJ Lussier, RAK Lopez… - The Canadian …, 2016 - pubs.geoscienceworld.org
Over the past four decades, the number of inorganic oxide and oxy-salt phases containing
stoichiometric quantities of hexavalent uranium has increased exponentially from a few …
stoichiometric quantities of hexavalent uranium has increased exponentially from a few …
Differentiating between trivalent lanthanides and actinides
The reactions of LnCl3 with molten boric acid result in the formation of Ln [B4O6 (OH)
2Cl](Ln= La–Nd), Ln4 [B18O25 (OH) 13Cl3](Ln= Sm, Eu), or Ln [B6O9 (OH) 3](Ln= Y, Eu …
2Cl](Ln= La–Nd), Ln4 [B18O25 (OH) 13Cl3](Ln= Sm, Eu), or Ln [B6O9 (OH) 3](Ln= Y, Eu …
Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides
This frontier article focuses on the use of flux crystal growth for the preparation of new
actinide containing materials, reviews the history of flux crystal growth of uranium containing …
actinide containing materials, reviews the history of flux crystal growth of uranium containing …
Bonding changes in plutonium (III) and americium (III) borates
Eine Frage der Größe: Drastische Unterschiede in der Reaktivität von Pu III‐und Am III‐
Zentren treten in geschmolzener Borsäure auf. Die resultierenden Komplexe haben …
Zentren treten in geschmolzener Borsäure auf. Die resultierenden Komplexe haben …
Comparison of thorium (IV) and uranium (VI) carboxyphosphonates
The hydrothermal reactions of thorium nitrate and uranyl acetate with
carboxyphenylphosphonic acid and HF result in the formation of ThF2 (PO3C6H4CO2H) …
carboxyphenylphosphonic acid and HF result in the formation of ThF2 (PO3C6H4CO2H) …
Syntheses, structures, luminescence, and photocatalytic properties of a series of uranyl coordination polymers
W Yang, WG Tian, XX Liu, L Wang… - Crystal growth & …, 2014 - ACS Publications
A new series of uranium coordination polymers have been hydrothermally synthesized by
using 4, 4′-oxidiphthalic acid (H4L) in the presence of N-bearing species, namely,(H2dpa) …
using 4, 4′-oxidiphthalic acid (H4L) in the presence of N-bearing species, namely,(H2dpa) …
Role of anions and reaction conditions in the preparation of uranium (VI), neptunium (VI), and plutonium (VI) borates
U (VI), Np (VI), and Pu (VI) borates with the formula AnO2 [B8O11 (OH) 4](An= U, Np, Pu)
have been prepared via the reactions of U (VI) nitrate, Np (VI) perchlorate, or Pu (IV) or Pu …
have been prepared via the reactions of U (VI) nitrate, Np (VI) perchlorate, or Pu (IV) or Pu …
Surprising coordination for plutonium in the first plutonium (III) borate
The first plutonium (III) borate, Pu2 [B12O18 (OH) 4Br2 (H2O) 3]· 0.5 H2O, has been
prepared by reacting plutonium (III) with molten boric acid under strictly anaerobic …
prepared by reacting plutonium (III) with molten boric acid under strictly anaerobic …