Biomimetic Frustrated Lewis Pair Catalysts for Hydrogenation of CO to Methanol at Low Temperatures

J Zhang, L Li, X **e, XQ Song… - ACS Organic & …, 2024 - ACS Publications
The industrial production of methanol through CO hydrogenation using the Cu/ZnO/Al2O3
catalyst requires harsh conditions, and the development of new catalysts with low operating …

Directed Evolution Enables Dynamic Control of Transient Intermediates for Anti-Markovnikov Wacker-Tsuji-Type Oxidation of Unactivated Alkenes

C Klaus, J Soler, G Kubik, Y Gumulya, Y Hui… - 2024 - chemrxiv.org
Controlling the dynamic behavior of highly reactive fleeting intermediates is an intriguing
concept to generate selectivity in competing reaction pathways. Here we report the directed …

1, 1, 1‐Trifluoro‐2‐Butanone

C Li - Encyclopedia of Reagents for Organic Synthesis, 2001 - Wiley Online Library
[381‐88‐4] CF3COC2H5 (MW 126.08) InChI= 1S/C4H5F3O/c1‐2‐3 (8) 4 (5, 6) 7/h2H2, 1H3
InChIKey= QBVHMPFSDVNFAY‐UHFFFAOYSA‐N (precursor of ethyl (trifluoromethyl) …