The renaissance of non‐aqueous uranium chemistry

ST Liddle - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

Recent developments in actinide–ligand multiple bonding

TW Hayton - Chemical Communications, 2013 - pubs.rsc.org
In the last few years, considerable progress has been made in the synthesis and
characterization of complexes containing actinide–ligand multiple bonds, especially in …

Synthesis and structure of a terminal uranium nitride complex

DM King, F Tuna, EJL McInnes, J McMaster, W Lewis… - Science, 2012 - science.org
The terminal uranium nitride linkage is a fundamental target in the study of f-orbital
participation in metal-ligand multiple bonding but has previously eluded characterization in …

C H Bond Activation by f‐Block Complexes

PL Arnold, MW McMullon, J Rieb… - Angewandte Chemie …, 2015 - Wiley Online Library
Most homogeneous catalysis relies on the design of metal complexes to trap and convert
substrates or small molecules to value‐added products. Organometallic lanthanide …

Isolation and characterization of a uranium(VI)–nitride triple bond

DM King, F Tuna, EJL McInnes, J McMaster… - Nature Chemistry, 2013 - nature.com
The nature and extent of covalency in uranium bonding is still unclear compared with that of
transition metals, and there is great interest in studying uranium–ligand multiple bonds …

A platinum(ii) metallonitrene with a triplet ground state

J Sun, J Abbenseth, H Verplancke, M Diefenbach… - Nature Chemistry, 2020 - nature.com
Metallonitrenes (M–N) are complexes with a subvalent atomic nitrogen ligand that have
been proposed as key reactive intermediates in nitrogen atom transfer reactions. However …

Photochemical synthesis of transition metal-stabilized uranium (VI) nitride complexes

X **n, I Douair, T Rajeshkumar, Y Zhao, S Wang… - Nature …, 2022 - nature.com
Uranium nitrides play important roles in dinitrogen activation and functionalization and in
chemistry for nuclear fuels, but the synthesis and isolation of the highly reactive uranium (VI) …

Recent progress in rare-earth metal-catalyzed sp 2 and sp 3 C–H functionalization to construct C–C and C–heteroelement bonds

K Seth - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
C–H functionalization is a fundamentally important organic transformation to access C–C
and C–heteroatom bonds in a common and/or complex molecular set-up during the …

Developments in the photophysics and photochemistry of actinide ions and their coordination compounds

LS Natrajan - Coordination Chemistry Reviews, 2012 - Elsevier
Actinide coordination chemistry is currently experiencing a renaissance, with the emergence
of exciting and less studied oxidation states, and previously unpredicted magnetic properties …

Closed-shell and open-shell square-planar iridium nitrido complexes

MG Scheibel, B Askevold, FW Heinemann… - Nature Chemistry, 2012 - nature.com
Coupling reactions of nitrogen atoms represent elementary steps to many important
heterogeneously catalysed reactions, such as the Haber–Bosch process or the selective …