The renaissance of non‐aqueous uranium chemistry
ST Liddle - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
Recent developments in actinide–ligand multiple bonding
TW Hayton - Chemical Communications, 2013 - pubs.rsc.org
In the last few years, considerable progress has been made in the synthesis and
characterization of complexes containing actinide–ligand multiple bonds, especially in …
characterization of complexes containing actinide–ligand multiple bonds, especially in …
Synthesis and structure of a terminal uranium nitride complex
DM King, F Tuna, EJL McInnes, J McMaster, W Lewis… - Science, 2012 - science.org
The terminal uranium nitride linkage is a fundamental target in the study of f-orbital
participation in metal-ligand multiple bonding but has previously eluded characterization in …
participation in metal-ligand multiple bonding but has previously eluded characterization in …
C H Bond Activation by f‐Block Complexes
PL Arnold, MW McMullon, J Rieb… - Angewandte Chemie …, 2015 - Wiley Online Library
Most homogeneous catalysis relies on the design of metal complexes to trap and convert
substrates or small molecules to value‐added products. Organometallic lanthanide …
substrates or small molecules to value‐added products. Organometallic lanthanide …
Isolation and characterization of a uranium(VI)–nitride triple bond
DM King, F Tuna, EJL McInnes, J McMaster… - Nature Chemistry, 2013 - nature.com
The nature and extent of covalency in uranium bonding is still unclear compared with that of
transition metals, and there is great interest in studying uranium–ligand multiple bonds …
transition metals, and there is great interest in studying uranium–ligand multiple bonds …
A platinum(ii) metallonitrene with a triplet ground state
J Sun, J Abbenseth, H Verplancke, M Diefenbach… - Nature Chemistry, 2020 - nature.com
Metallonitrenes (M–N) are complexes with a subvalent atomic nitrogen ligand that have
been proposed as key reactive intermediates in nitrogen atom transfer reactions. However …
been proposed as key reactive intermediates in nitrogen atom transfer reactions. However …
Photochemical synthesis of transition metal-stabilized uranium (VI) nitride complexes
Uranium nitrides play important roles in dinitrogen activation and functionalization and in
chemistry for nuclear fuels, but the synthesis and isolation of the highly reactive uranium (VI) …
chemistry for nuclear fuels, but the synthesis and isolation of the highly reactive uranium (VI) …
Recent progress in rare-earth metal-catalyzed sp 2 and sp 3 C–H functionalization to construct C–C and C–heteroelement bonds
K Seth - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
C–H functionalization is a fundamentally important organic transformation to access C–C
and C–heteroatom bonds in a common and/or complex molecular set-up during the …
and C–heteroatom bonds in a common and/or complex molecular set-up during the …
Developments in the photophysics and photochemistry of actinide ions and their coordination compounds
LS Natrajan - Coordination Chemistry Reviews, 2012 - Elsevier
Actinide coordination chemistry is currently experiencing a renaissance, with the emergence
of exciting and less studied oxidation states, and previously unpredicted magnetic properties …
of exciting and less studied oxidation states, and previously unpredicted magnetic properties …
Closed-shell and open-shell square-planar iridium nitrido complexes
MG Scheibel, B Askevold, FW Heinemann… - Nature Chemistry, 2012 - nature.com
Coupling reactions of nitrogen atoms represent elementary steps to many important
heterogeneously catalysed reactions, such as the Haber–Bosch process or the selective …
heterogeneously catalysed reactions, such as the Haber–Bosch process or the selective …