A series of boron based Lewis acids have been reported to date, but among them, tris
(pentafluorophenyl) borane (BCF) has gained the most significant attention in the synthetic …

Hydrosilylation of carbonyl compounds gives the corresponding silyl ethers in the presence
of various catalysts. Previously, transition metals and metal halides, such as Ni, NiCl2 …

The design of new materials with tunable properties and intrinsic recyclability, derived from
biomass under mild conditions, stands as a gold standard in polymer chemistry. Reported …

Silanes are important in chemistry and material science. The self‐redistribution of HSiCl3 is
an industrial process to prepare SiH4, which is widely used in electronics and automobile …

With the rapid development of integrated circuit (IC) chips towards nanometric
miniaturization, advanced integration and high performance, interlayer dielectric (ILD) …

We report metal-free B (C6F5) 3-catalysed hydrosilylation polymerization for alternating
silylether–carbosilane copolymers. The reaction was carried out at room temperature using …

This report communicates the first example of polymer backbone metamorphosis affected by
anionic 1, 2-Brook rearrangement of acyl silane moieties. Introduction of the acyl silane …

Sila-isosteres have attracted increasing attention due to their potential application in a
variety of fields and their different properties compared to their carbon-containing analogs …

Polymer research is currently focused on sustainable and degradable polymers which are
cheap, easy to synthesize, and environmentally friendly. Silicon-based polymers are …

Synthetic polymers are indispensable in biomedical applications because they can be
fabricated with consistent and reproducible properties, facile scalability, and customizable …