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Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …
polaritons, are formed due to quantum light–matter interactions. With the experimental …
Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
Recent developments in Kramers' theory of reaction rates
In this short review, we provide an update of recent developments in Kramers' theory of
reaction rates. After a brief introduction stressing the importance of this theory initially …
reaction rates. After a brief introduction stressing the importance of this theory initially …
Resonance theory of vibrational strong coupling enhanced polariton chemistry and the role of photonic mode lifetime
Recent experiments demonstrate polaritons under the vibrational strong coupling (VSC)
regime can modify chemical reactivity. Here, we present a complete theory of VSC-modified …
regime can modify chemical reactivity. Here, we present a complete theory of VSC-modified …
Investigating the collective nature of cavity-modified chemical kinetics under vibrational strong coupling
In this paper, we develop quantum dynamical methods capable of treating the dynamics of
chemically reacting systems in an optical cavity in the vibrationally strong-coupling (VSC) …
chemically reacting systems in an optical cavity in the vibrationally strong-coupling (VSC) …
Beyond cavity Born–Oppenheimer: On nonadiabatic coupling and effective ground state Hamiltonians in vibro-polaritonic chemistry
The emerging field of vibro-polaritonic chemistry studies the impact of light–matter hybrid
states known as vibrational polaritons on chemical reactivity and molecular properties. Here …
states known as vibrational polaritons on chemical reactivity and molecular properties. Here …
Polaritonic Chemistry Enabled by Non‐Local Metasurfaces
Vibrational strong coupling can modify chemical reaction pathways in unconventional ways.
Thus far, Fabry‐Perot cavities formed by pairs of facing mirrors have been mostly utilized to …
Thus far, Fabry‐Perot cavities formed by pairs of facing mirrors have been mostly utilized to …
[HTML][HTML] Understanding the cavity Born–Oppenheimer approximation
Experiments have demonstrated that vibrational strong coupling between molecular
vibrations and light modes can significantly change molecular properties, such as ground …
vibrations and light modes can significantly change molecular properties, such as ground …
Resonance theory of vibrational polariton chemistry at the normal incidence
We present a theory that explains the resonance effect of the vibrational strong coupling
(VSC) modified reaction rate constant at the normal incidence of a Fabry–Pérot (FP) cavity …
(VSC) modified reaction rate constant at the normal incidence of a Fabry–Pérot (FP) cavity …
On the mechanism of polaritonic rate suppression from quantum transition paths
Polariton chemistry holds promise for facilitating mode-selective chemical reactions, but the
underlying mechanism behind the rate modifications observed under strong vibrational …
underlying mechanism behind the rate modifications observed under strong vibrational …