Spatially and temporally understanding dynamic solid–electrolyte interfaces in carbon dioxide electroreduction

J Wang, HY Tan, MY Qi, JY Li, ZR Tang… - Chemical Society …, 2023 - pubs.rsc.org
The ubiquity of solid–liquid interfaces in nature and the significant role of their atomic-scale
structure in determining interfacial properties have led to intensive research. Particularly in …

Electrocatalysis in alkaline media and alkaline membrane-based energy technologies

Y Yang, CR Peltier, R Zeng, R Schimmenti, Q Li… - Chemical …, 2022 - ACS Publications
Hydrogen energy-based electrochemical energy conversion technologies offer the promise
of enabling a transition of the global energy landscape from fossil fuels to renewable energy …

The hydrogen evolution reaction: from material to interfacial descriptors

N Dubouis, A Grimaud - Chemical Science, 2019 - pubs.rsc.org
The production of sustainable hydrogen with water electrolyzers is envisaged as one of the
most promising ways to match the continuously growing demand for renewable electricity …

The interrelated effect of cations and electrolyte pH on the hydrogen evolution reaction on gold electrodes in alkaline media

A Goyal, MTM Koper - Angewandte Chemie International …, 2021 - Wiley Online Library
In this work we study the role of alkali metal cation concentration and electrolyte pH in
altering the kinetics of the hydrogen evolution reaction (HER) at gold (Au) electrodes. We …

Bonds over electrons: proton coupled electron transfer at solid–solution interfaces

JM Mayer - Journal of the American Chemical Society, 2023 - ACS Publications
This Perspective argues that most redox reactions of materials at an interface with a protic
solution involve net proton-coupled electron transfer (PCET)(or other cation-coupled ET) …

Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes

I Ledezma-Yanez, WDZ Wallace, P Sebastián-Pascual… - Nature Energy, 2017 - nature.com
Hydrogen evolution on platinum is a key reaction for electrocatalysis and sustainable energy
storage, yet its pH-dependent kinetics are not fully understood. Here we present a detailed …

“Beyond adsorption” descriptors in hydrogen electrocatalysis

L Rebollar, S Intikhab, NJ Oliveira, Y Yan, B Xu… - ACS …, 2020 - ACS Publications
Although electrochemical hydrogen evolution and oxidation are arguably the best-
understood reactions in electrocatalysis, the anomalous effect of pH on hydrogen reaction …

How to Assess and Predict Electrical Double Layer Properties. Implications for Electrocatalysis

CM Schott, PM Schneider, KT Song, H Yu… - Chemical …, 2024 - ACS Publications
The electrical double layer (EDL) plays a central role in electrochemical energy systems,
impacting charge transfer mechanisms and reaction rates. The fundamental importance of …

Acoustically‐Induced Water Frustration for Enhanced Hydrogen Evolution Reaction in Neutral Electrolytes

Y Ehrnst, PC Sherrell, AR Rezk… - Advanced Energy …, 2023 - Wiley Online Library
A novel strategy utilizing high‐frequency (10 MHz) hybrid sound waves to dramatically
enhance hydrogen evolution reactions (HER) in notoriously difficult neutral electrolytes by …

Disentangling charge carrier from photothermal effects in plasmonic metal nanostructures

C Zhan, BW Liu, YF Huang, S Hu, B Ren… - Nature …, 2019 - nature.com
Plasmon-mediated chemical reactions (PMCRs) constitute a vibrant research field,
advancing such goals as using sunlight to convert abundant precursors such as CO2 and …