MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide
Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …
covalent organic frameworks (COFs), have been widely used in energy-related conversion …
Metal–organic framework-based catalysts with single metal sites
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
Lattice-strained metal–organic-framework arrays for bifunctional oxygen electrocatalysis
Oxygen electrocatalysis is central to technologies such as fuel cells and electrolysers, but
challenges remain due to the lack of effective earth-abundant electrocatalysts and …
challenges remain due to the lack of effective earth-abundant electrocatalysts and …
Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
Metal-organic frameworks for catalysis: State of the art, challenges, and opportunities
Abstract Metal-organic frameworks (MOFs), also known as porous coordination polymers
(PCPs), are a unique class of porous crystalline materials that are constructed by metal …
(PCPs), are a unique class of porous crystalline materials that are constructed by metal …
A historical perspective on porphyrin-based metal–organic frameworks and their applications
Porphyrins are important molecules widely found in nature in the form of enzyme active sites
and visible light absorption units. Recent interest in using these functional molecules as …
and visible light absorption units. Recent interest in using these functional molecules as …
Enzyme‐inspired iron porphyrins for improved electrocatalytic oxygen reduction and evolution reactions
L **e, XP Zhang, B Zhao, P Li, J Qi, X Guo… - Angewandte …, 2021 - Wiley Online Library
Nature uses Fe porphyrin sites for the oxygen reduction reaction (ORR). Synthetic Fe
porphyrins have been extensively studied as ORR catalysts, but activity improvement is …
porphyrins have been extensively studied as ORR catalysts, but activity improvement is …
Surface-supported metal–organic framework thin films: fabrication methods, applications, and challenges
Surface-supported metal–organic framework thin films are receiving increasing attention as
a novel form of nanotechnology. New deposition techniques that enable the control of the …
a novel form of nanotechnology. New deposition techniques that enable the control of the …
Bimetallic metal–organic frameworks and MOF-derived composites: Recent progress on electro-and photoelectrocatalytic applications
Owing to the growing demand in areas such as energy, environmental science, electro-and
photoelectrocatalysis, different reactions such as HER (hydrogen evolution), OER (oxygen …
photoelectrocatalysis, different reactions such as HER (hydrogen evolution), OER (oxygen …